Entrapping an Ionic Liquid with Nanocarbon: The Formation of a Tailorable and Functional Surface

被引：67

作者：

Ding, Yuxiao ^{[1
]}

Sun, Xiaoyan ^{[1
]}

Zhang, Liyun ^{[1
]}

Mao, Shanjun ^{[1
]}

Xie, Zailai ^{[2
]}

Liu, Zhong-Wen ^{[3
]}

Su, Dang Sheng ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China

[2] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany

[3] Shaanxi Normal Univ, Key Lab Appl Surface & Colloid Chem MOE, Xian 710062, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 01期

关键词：

interfaces; ionic liquids; nanocarbons; nanocomposites; surface modification; MULTIWALLED CARBON NANOTUBES; DOPED CARBON; SPECTROSCOPY; PRECURSORS;

D O I：

10.1002/anie.201408201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An interface microenvironment between nanocarbon and ionic liquids (ILs) is presented. By an entrapping effect, a few layers of ILs can be finely deposited on the surface of nanocarbon, endowing amazingly tailorable surface properties. The entrapped IL layer, which was believed to be unable to be charred under pyrolysis conditions alone, can be further carbonized to a functional carbon layer. C, B, and N were confirmed to share the same hexagonal ring in the resultant layer, which provides more designable electronic properties.

引用

页码：231 / 235

页数：5

共 24 条

[1]

[Anonymous], 2012, ANGEW CHEM, V124, P8618

[2] Thin-walled, mesoporous and nitrogen-doped hollow carbon spheres using ionic liquids as precursors [J].

Chen, Aibing ;

Yu, Yifeng ;

Lv, Haijun ;

Wang, Yanyan ;

Shen, Shufeng ;

Hu, Yongqi ;

Li, Bo ;

Zhang, Yue ;

Zhang, Jian .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (04) :1045-1047

[3] Transition of ionic liquid [bmim][PF6] from liquid to high-melting-point crystal when confined in multiwalled carbon nanotubes [J].

Chen, Shimou ;

Wu, Guozhong ;

Sha, Maolin ;

Huang, Shirong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (09) :2416-+

[4] RAMAN MICROPROBE STUDIES ON CARBON MATERIALS [J].

CUESTA, A ;

DHAMELINCOURT, P ;

LAUREYNS, J ;

MARTINEZALONSO, A ;

TASCON, JMD .

CARBON, 1994, 32 (08) :1523-1532

[5] Host-Guest Nanocomposites of Multiwalled Carbon Nanotubes and Ionic Liquids with Controllable Composition [J].

Ding, Yuxiao ;

Su, Dang Sheng .

CHEMSUSCHEM, 2014, 7 (06) :1542-1546

[6] NIR FT Raman spectroscopic study of flame soot [J].

Dippel, B ;

Jander, H ;

Heintzenberg, J .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (20) :4707-4712

[7] The distillation and volatility of ionic liquids [J].

Earle, MJ ;

Esperança, JMSS ;

Gilea, MA ;

Lopes, JNC ;

Rebelo, LPN ;

Magee, JW ;

Seddon, KR ;

Widegren, JA .

NATURE, 2006, 439 (7078) :831-834

[8] 25th Anniversary Article: "Cooking Carbon with Salt": Carbon Materials and Carbonaceous Frameworks from Ionic Liquids and Poly(ionic liquid)s [J].

Fellinger, Tim-Patrick ;

Thomas, Arne ;

Yuan, Jiayin ;

Antonietti, Markus .

ADVANCED MATERIALS, 2013, 25 (41) :5838-5854

[9] Mesoporous Nitrogen-Doped Carbon for the Electrocatalytic Synthesis of Hydrogen Peroxide [J].

Fellinger, Tim-Patrick ;

Hasche, Frederic ;

Strasser, Peter ;

Antonietti, Markus .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (09) :4072-4075

[10] Molecular ordering of organic molten salts triggered by single-walled carbon nanotubes [J].

Fukushima, T ;

Kosaka, A ;

Ishimura, Y ;

Yamamoto, T ;

Takigawa, T ;

Ishii, N ;

Aida, T .

SCIENCE, 2003, 300 (5628) :2072-2074

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