The reaction of Wittig-Horner reagents and phosphacumulenes with nitrosonaphthol

被引：14
作者：
Boulos, LS [1 ]
Arsanious, MHN [1 ]
El-Din, NK [1 ]
机构：
[1] Natl Res Ctr, Cairo, Egypt
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1997年 / 122卷
关键词：
Wittig-Horner reagents (1a-c); phosphacumulene (2); 2-nitroso-1-naphtho1; 3; the alkylated product 4; the olefinic adducts 5; the dimeric product 6; the phosphonate adducts 8a; b and the; phosphonnylidene cyclobutylidene adduct 10;
D O I：
10.1080/10426509708043494
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Wittig-Horner reagent la reacts with 2-nitroso-1-naphthol 3 to give the olefinic adduct 5, the alkylated product 4 and the dimeric compound 6. When 2-nitroso-1-naphthol 3 reacts with Wittig-Homer reagents 1b,c, the corresponding phosphonate adducts 8a,b together with compounds 4 and 6 were obtained. Oxovinylidenetriphenylphosphorane 2 reacts with 3 to give the corresponding phosphoranylidenecyclobutylidene adduct 10 and triphenylphosphine oxide. The structural assignments of the new products are based on compatible analytical and spectroscopic results.
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页码：49 / 58
页数：10
相关论文
共 22 条
[1]  
Bestmann H.J., 1976, ANGEW CHEM, V88, P92, DOI DOI 10.1002/ANGE.19760880311
[2]   NEW SYNTHESIS OF KETENIMINYLIDENETRIPHENYLPHOSPHORANES AND THIOKETENYLIDENETRIPHENYLPHOSPHORANE [J].
BESTMANN, HJ ;
SCHMID, G .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1974, 13 (04) :273-274
[3]  
BESTMANN HJ, 1977, ANGEW CHEM, V89, P361
[4]   THE BEHAVIOR OF PARA-QUINONES TOWARDS WITTIG-HORNER REAGENTS [J].
BOULOS, LS ;
ELRAHMAN, NMA .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1991, 62 (1-4) :163-167
[5]   THE REACTION OF WADSWORTH-EMMONS-HORNER REAGENTS WITH O-QUINONEIMINES AND P-QUINONEIMINES [J].
BOULOS, LS ;
ARSANIOUS, MHN .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1994, 89 (1-4) :185-191
[6]  
BOULOS LS, 1992, PHOSPHORUS SULFUR SI, V68, P240
[7]  
CADOGAN JIG, 1975, ORGANOPHOSPHORUS REA
[8]  
CLERC P, 1983, TABLES SPECTRAL DATA, P1235
[9]  
CRAFTS PC, 1958, Q REV CHEM SOC, V21, P341
[10]  
CRUTCHFIELD MM, 1967, TOPICS PHOSPHORUS CH, P5
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