Synthesis and Structure of Zn(II) Complexes with Cyclobutane-1,1-Dicarboxylic Acid Anions and Calcium and Barium Cations

被引：7
|
作者：
Zorina-Tikhonova, E. N. [1 ]
Chistyakov, A. S. [1 ]
Kiskin, M. A. [1 ]
Vologzhanina, A. V. [2 ]
Sidorov, A. A. [1 ]
Eremenko, I. L. [1 ,2 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow, Russia
[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2021年 / 47卷 / 06期
关键词：
coordination polymers; zinc; dicarboxylic acids; cyclobutane-1; 1-dicarboxylic acid; X-ray diffraction; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; POLYHEDRAL STRUCTURES; ODD NUMBER; PHOTOLUMINESCENCE; VERTICES; SHAPE;
D O I：
10.1134/S1070328421060099
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New zinc(II) compounds with cyclobutane-1,1-dicarboxylic acid (H(2)Cbdc) anions and calcium [CaZn(Cbdc)(2)(H2O)(3)](n) (I) and barium [BaZn(Cbdc)(2)(H2O)(2)](n) (II) cations were obtained. According to X-ray diffraction data (CIF files CCDC nos. 2055176 (I), 2055177 (II)), compounds I and II are coordination polymers in which zinc atoms are connected by bridging and chelating-bridging acid dianions to form 2D architectures with a square lattice topology. Alkaline earth metal atoms do not affect the dimensionality of compound packing.
引用
收藏
页码：409 / 416
页数：8
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