Exploring the gold mine: [Au]-catalysed transformations of enynals, enynones and enynols

被引：91

作者：

Kumari, A. Leela Siva ^{[1
]}

Reddy, Alla Siva ^{[1
]}

Swamy, K. C. Kumara ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Telangana, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 28期

关键词：

HIGHLY EFFICIENT SYNTHESIS; CYCLIZATION/OXIDATIVE CLEAVAGE REACTIONS; CATALYZED HYDRATIVE CARBOCYCLIZATION; ONE-POT SYNTHESIS; SUBSTITUTED FURANS; 4+2 BENZANNULATION; O-ALKYNYLBENZALDEHYDES; CASCADE; CYCLOADDITION; TANDEM;

D O I：

10.1039/c6ob00698a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Gold catalysed synthesis of carbo-/hetero-cyclic compounds is currently a topic of intense activity thanks to the unique properties bestowed upon gold by relativistic effects, the potential of which has been realised mainly during the past two decades. This review will dwell upon the reactions involving gold catalysis in which enynal, enynone or enynol is one of the reacting partners. Most often these reactions lead to fused hetero-/homo-cycles under mild conditions with environmentally benign byproducts. Thus an opportunity for the organic community to develop new methodologies, efficient asymmetric variants, and application in total synthesis by [Au]-catalysis has emerged.

引用

页码：6651 / 6671

页数：21

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