Large area tunnel oxide passivated rear contact n-type Si solar cells with 21.2% efficiency

被引:75
作者
Tao, Yuguo [1 ]
Upadhyaya, Vijaykumar [1 ]
Chen, Chia-Wei [1 ]
Payne, Adam [2 ]
Chang, Elizabeth Lori [1 ]
Upadhyaya, Ajay [1 ]
Rohatgi, Ajeet [1 ,2 ]
机构
[1] Georgia Inst Technol, 777 Atlantic Dr, Atlanta, GA 30332 USA
[2] Suniva Inc, 5765 Peachtree Ind Blvd, Norcross, GA 30092 USA
来源
PROGRESS IN PHOTOVOLTAICS | 2016年 / 24卷 / 06期
关键词
tunnel oxide; passivated contact; room temperature; large area; n-type Cz wafer; screen-printed; ELECTRON;
D O I
10.1002/pip.2739
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This paper reports on the implementation of carrier-selective tunnel oxide passivated rear contact for high-efficiency screen-printed large area n-type front junction crystalline Si solar cells. It is shown that the tunnel oxide grown in nitric acid at room temperature (25 degrees C) and capped with n(+) polysilicon layer provides excellent rear contact passivation with implied open-circuit voltage iV(oc) of 714mV and saturation current density J(ob)' of 10.3 fA/cm(2) for the back surface field region. The durability of this passivation scheme is also investigated for a back-end high temperature process. In combination with an ion-implanted Al2O3-passivated boron emitter and screen-printed front metal grids, this passivated rear contact enabled 21.2% efficient front junction Si solar cells on 239 cm(2) commercial grade n-type Czochralski wafers. Copyright (C) 2016 John Wiley & Sons, Ltd.
引用
收藏
页码:830 / 835
页数:6
相关论文
共 33 条
[1]   Models for numerical device simulations of crystalline silicon solar cells-a review [J].
Altermatt, Pietro P. .
JOURNAL OF COMPUTATIONAL ELECTRONICS, 2011, 10 (03) :314-330
[2]   Improving the a-Si:H(p) rear emitter contact of n-type silicon solar cells [J].
Bivour, Martin ;
Reichel, Christian ;
Hermle, Martin ;
Glunz, Stefan W. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 106 :11-16
[3]   Fully Ion Implanted and Coactivated Industrial n-Type Cells With 20.5% Efficiency [J].
Boescke, T. S. ;
Kania, D. ;
Schoellhorn, C. ;
Stichtenoth, D. ;
Helbig, A. ;
Sadler, P. ;
Braun, M. ;
Dupke, M. ;
Weiss, M. ;
Grohe, A. ;
Lossen, J. ;
Krokoszinski, H. -J. .
IEEE JOURNAL OF PHOTOVOLTAICS, 2014, 4 (01) :48-51
[4]   Metallization-induced recombination losses of bifacial silicon solar cells [J].
Edler, Alexander ;
Mihailetchi, Valentin D. ;
Koduvelikulathu, Lejo J. ;
Comparotto, Corrado ;
Kopecek, Radovan ;
Harney, Rudolf .
PROGRESS IN PHOTOVOLTAICS, 2015, 23 (05) :620-627
[5]   Tunnel oxide passivated contacts as an alternative to partial rear contacts [J].
Feldmann, Frank ;
Bivour, Martin ;
Reichel, Christian ;
Steinkemper, Heiko ;
Herm, Martin ;
Glunz, Stefan W. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2014, 131 :46-50
[6]   Efficient carrier-selective p- and n-contacts for Si solar cells [J].
Feldmann, Frank ;
Simon, Maik ;
Bivour, Martin ;
Reichel, Christian ;
Hermle, Martin ;
Glunz, Stefan W. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2014, 131 :100-104
[7]   Passivated rear contacts for high-efficiency n-type Si solar cells providing high interface passivation quality and excellent transport characteristics [J].
Feldmann, Frank ;
Bivour, Martin ;
Reichel, Christian ;
Hermle, Martin ;
Glunz, Stefan W. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2014, 120 :270-274
[8]   >23% High-Efficiency Tunnel Oxide Junction Bifacial Solar Cell With Electroplated Cu Gridlines [J].
Heng, Jiunn Benjamin ;
Fu, Jianming ;
Kong, Bob ;
Chae, Yongkee ;
Wang, Wei ;
Xie, Zhigang ;
Reddy, Anand ;
Lam, Kevin ;
Beitel, Chris ;
Liao, Chris ;
Erben, Christoph ;
Huang, Zhiquan ;
Xu, Zheng .
IEEE JOURNAL OF PHOTOVOLTAICS, 2015, 5 (01) :82-86
[9]  
Hermle M., 2011, Proceedings of the 26th European International Conference on Photovoltaic Solar Energy, P875
[10]   Excellent passivation of highly doped p-type Si surfaces by the negative-charge-dielectric Al2O3 [J].
Hoex, B. ;
Schmidt, J. ;
Bock, R. ;
Altermatt, P. P. ;
van de Sanden, M. C. M. ;
Kessels, W. M. M. .
APPLIED PHYSICS LETTERS, 2007, 91 (11)