The excited-state intramolecular proton transfer properties of three imine-linked two-dimensional porous organic polymers

被引:36
作者
Jagadesan, Pradeepkumar [1 ]
Eder, Grace [1 ]
McGrier, Psaras L. [1 ]
机构
[1] Ohio State Univ, Dept Chem & Biochem, 100 W 18th Ave, Columbus, OH 43210 USA
基金
美国国家科学基金会;
关键词
TRANSFER ESIPT; MECHANISM; FLUORESCENCE; FRAMEWORKS; EMISSION; CO2; CHROMOPHORES; STABILITY; CATALYSIS; STORAGE;
D O I
10.1039/c7tc00123a
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report the synthesis and excited-state intramolecular proton transfer (ESIPT) properties of three tris(N-salicylideneaniline)-based (TSA) imine-linked porous organic polymers (POPs) containing C-3-symmetric 1,3,5-triarylbenzene (TAB), -tristyrylbenzene (TSB), and -tris(arylethynyl) benzene (TAE) monomer units. The TSA-POPs are fluorescent in the solid-state and responsive to Cu2+ and Pd2+.
引用
收藏
页码:5676 / 5679
页数:4
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