Syntheses, structural characterization and luminescent properties of M2(ATPA)3(DMF)2(H2O)2 (M = Nd, Sm, Eu, Gd, Tb, Dy; ATPA=2-aminoterephthalate, DMF = N,N-dimethylformamide)

被引：13
作者：
Liao, Ju-Hsiou [1 ]
Tsai, Cherng-Shiaw [1 ]
Lin, Tsu-Kai [1 ]
机构：
[1] Natl Chung Cheng Univ, Dept Chem & Biochem, Chiayi 621, Taiwan
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 02期
关键词：
Metal-organic frameworks; 2-Aminoterephthalate; Lanthanide; Luminescence; Magnetic; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; COORDINATION POLYMERS; DESIGN;
D O I：
10.1016/j.inoche.2009.12.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Six isomorphous metal-organic frameworks: M-2(ATPA)(3)(DMF)(2)(H2O)(2) (M = Nd (1), Sm (2), Eu (3), Gd (4). Tb (5), Dy (6); ATPA = 2-aminoterephthalate, DMF = N,N-dimethylformamide), were synthesized by the self-assembly of lanthanide ions, 2-aminoterephthalate, DMF and H2O. Their crystal structures determined by X-ray crystallography reveal interpenetrating frameworks. Compounds 2, 3, 5 and, 6 exhibit mainly ligand luminescence at room temperature while 3 exhibits enhanced Eu3+ emissions at 77 K. Magnetic studies indicate 4 is paramagnetic with slight Gd3+-Gd3+ couplings. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：286 / 289
页数：4
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