Synthesis of tri(m-sulfonatedphenyl)phosphine (TPPTS): The importance of pH in the work-up

被引：27

作者：

Hida, S ^{[1
]}

Roman, PJ ^{[1
]}

Bowden, AA ^{[1
]}

Atwood, JD ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1998年 / 43卷 / 04期

关键词：

TPPTS; water soluble; sulfonated ligands;

D O I：

10.1080/00958979808230447

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Controlling the pH during workup allows synthesis of TPPTS, P(m-C6H4SO3Na)(3), without interference from the oxide. The recrystallized yield is 70% based on P(m-C6H4SO3Na)(3) . 3H(2)O from PPh3.

引用

页码：345 / 348

页数：4

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