Hydrodeoxygenation of Lignin-Derived Phenols into Alkanes by Using Nanoparticle Catalysts Combined with Bronsted Acidic Ionic Liquids

被引：282

作者：

Yan, Ning ^{[1
]}

Yuan, Yuan ^{[1
]}

Dykeman, Ryan ^{[1
]}

Kou, Yuan ^{[2
]}

Dyson, Paul J. ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

[2] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, PKU Green Chem Ctr, Beijing 100871, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 32期

关键词：

biofuels; ionic liquids; lignin; nanoparticle catalysis; tandem catalysis; COPOLYMER STABILIZED NANOCATALYSTS; FAST PYROLYSIS; BIO-OIL; BIPHASIC HYDROGENATION; RHODIUM NANOPARTICLES; SOLVOLYSIS LIGNIN; KRAFT LIGNIN; BIODIESEL; CONVERSION; WOOD;

D O I：

10.1002/anie.201001531

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxy-gone in a tandem: A catalytic system composed of metal nanoparticles (NPs) and a functionalized Brensted acidic ionic liquid (IL), both of which are immobilized in a nonfunctionalized IL, is highly efficient in upgrading lignin-derived phenolic compounds into alkanes; the hydrogenation and dehydration reactions take place in tandem. Figure Presented © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5549 / 5553

页数：5

共 57 条

[1] Extraction of glycerol from biodiesel into a eutectic based ionic liquid [J].

Abbott, Andrew P. ;

Cullis, Paul M. ;

Gibson, Manda J. ;

Harris, Robert C. ;

Raven, Emma .

GREEN CHEMISTRY, 2007, 9 (08) :868-872

[2]

Albertazzi S., 2007, CATALYSIS RENEWABLES, P147

[3]

[Anonymous], [No title captured], Patent No. 5180868

[4]

[Anonymous], 2009, ANGEW CHEM-GER EDIT, DOI DOI 10.1002/ANGE.200900404

[5] Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis [J].

Astruc, D ;

Lu, F ;

Aranzaes, JR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (48) :7852-7872

[6]

Astruc D., 2005, Angew. Chem, V117, P8062, DOI DOI 10.1002/ange.200500766

[7]

AUGUSTINE RL, 1996, HETEROGENEOUS CATALY, pCH17

[8]

BASTIEN L, 2008, INORG CHEM, V47, P9090

[9] Reactions of lignin model compounds in ionic liquids [J].

Binder, Joseph B. ;

Gray, Michel J. ;

White, James F. ;

Zhang, Z. Conrad ;

Holladay, Johnathan E. .

BIOMASS & BIOENERGY, 2009, 33 (09) :1122-1130

[10] Production of bio-oil from alfalfa stems by fluidized-bed fast pyrolysis [J].

Boateng, Akwasi A. ;

Mullen, Charles A. ;

Goldberg, Neil ;

Hicks, Kevin B. ;

Jung, Hans-Joachim G. ;

Lamb, JoAnn F. S. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (12) :4115-4122

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