Effect of pH, Surfactant, and Temperature on Mixed-Phase Structure and Band Gap Properties of BiNbO4 Nanoparticles Prepared Using Different Routes

被引:10
作者
Bakiro, Maram [1 ]
Hussein Ahmed, Salwa [1 ]
Alzamly, Ahmed [1 ]
机构
[1] UAE Univ, Dept Chem, POB 15551, Al Ain, U Arab Emirates
来源
CHEMISTRY-SWITZERLAND | 2019年 / 1卷 / 01期
关键词
BiNbO4; co-precipitation; hydrothermal; citrate precursor; bandgap; visible light; METAL-OXIDES; HIGH-PRESSURE; TRANSITION; FILMS;
D O I
10.3390/chemistry1010008
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
alpha- and beta-BiNbO4 nanoparticles were successfully prepared using three different routes, namely co-precipitation, hydrothermal, and citrate precursor methods. Structural characterization has been analyzed using powder X-ray diffraction where results confirmed the mixed-phase nature of the prepared powders. When co-precipitation method is applied, BiNbO4 prepared at pH 2 and calcined at 750 degrees C shows predominately the alpha-BiNbO4 owning the narrowest band gap of 2.86 eV, whereas an increase in the pH value resulted in the beta-BiNbO4 phase being the predominant phase. On the other hand, samples prepared using citrate precursor method show co-existence of both alpha- and beta-BiNbO4 at all pH values under study; however, at pH 10 the beta-BiNbO4 was the dominant phase exhibiting a higher bandgap energy value of 3.16 eV. When applying the hydrothermal approach, BiNbO4 prepared at all pH ranges of the present study show a band gap >3.2 eV indicating their activity in the ultraviolet region of the spectrum. Moreover, increasing calcination temperature to 900 degrees C, a gradual transformation of alpha- to beta was observed. Lastly, it was noticed that as the lattice volume increases, the band gap of prepared BiNbO4 decreases.
引用
收藏
页码:89 / 110
页数:22
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