Saving transverse magnetization

被引:1
作者
Kobayashi, Takeshi [1 ]
DiVerdi, Joseph A. [1 ]
Faulkner, Rebecca A. [1 ]
Maciel, Gary E. [1 ]
机构
[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
关键词
Magnetization storage; Transverse magnetization; Carr-Purcell sequence; Store-and-restore; CHEMICAL-SHIFT-ANISOTROPY; NMR-SPECTROSCOPY; SOLIDS; RELAXATION; AXIS;
D O I
10.1016/j.ssnmr.2009.12.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A magnetization storage sequence, ALT-1 (alternating longitudinal and transverse components), is reported. The ALT-1 sequence is a hybrid of two types of storage sequences, the Carr-Purcell type and store-and-restore sequences. During incremental storage periods within the ALT-1 sequence, essentially half of the initially transverse magnetization is stored along the z-axis and the other half is prolonged by an echo-generating pulse. The portions of initial magnetization that are stored as longitudinal components or transverse components are alternated by a pi/2 pulse during the cycle. Both transverse components of the initial magnetization are treated the same in the ALT-1 sequence and orientational (phase) information of the initial magnetization is kept during the storage period. The ALTA sequence can preserve magnetization more effectively than a published class of modified Carr-Purcell type sequences, because essentially half of the magnetization during incremental storage periods is not subjected to relaxation from T-2 effects. (C) 2009 Elsevier Inc. All rights reserved.
引用
收藏
页码:202 / 208
页数:7
相关论文
共 22 条
[1]   CORRELATION OF ISOTROPIC SHIFTS AND CHEMICAL-SHIFT ANISOTROPIES BY TWO-DIMENSIONAL FOURIER-TRANSFORM MAGIC-ANGLE HOPPING NMR-SPECTROSCOPY [J].
BAX, A ;
SZEVERENYI, NM ;
MACIEL, GE .
JOURNAL OF MAGNETIC RESONANCE, 1983, 52 (01) :147-152
[2]   CHEMICAL-SHIFT ANISOTROPY IN POWDERED SOLIDS STUDIED BY 2D FT NMR WITH FLIPPING OF THE SPINNING AXIS [J].
BAX, A ;
SZEVERENYI, NM ;
MACIEL, GE .
JOURNAL OF MAGNETIC RESONANCE, 1983, 55 (03) :494-497
[3]   TWO-DIMENSIONAL CHEMICAL-SHIFT-ANISOTROPY CORRELATION SPECTROSCOPY [J].
CARTER, CM ;
ALDERMAN, DW ;
GRANT, DM .
JOURNAL OF MAGNETIC RESONANCE, 1985, 65 (01) :183-186
[4]   Low-power decoupling in fast magic-angle spinning NMR [J].
Ernst, M ;
Samoson, A ;
Meier, BH .
CHEMICAL PHYSICS LETTERS, 2001, 348 (3-4) :293-302
[5]   Time-of-flight flow imaging using NMR remote detection [J].
Granwehr, J ;
Harel, E ;
Han, S ;
Garcia, S ;
Pines, A ;
Sen, PN ;
Song, YQ .
PHYSICAL REVIEW LETTERS, 2005, 95 (07)
[6]   ROTATIONAL-ECHO DOUBLE-RESONANCE NMR [J].
GULLION, T ;
SCHAEFER, J .
JOURNAL OF MAGNETIC RESONANCE, 1989, 81 (01) :196-200
[7]   NEW, COMPENSATED CARR-PURCELL SEQUENCES [J].
GULLION, T ;
BAKER, DB ;
CONRADI, MS .
JOURNAL OF MAGNETIC RESONANCE, 1990, 89 (03) :479-484
[8]   STRUCTURAL INVESTIGATIONS BY MEANS OF NUCLEAR MAGNETISM .2. HINDERED ROTATION IN SOLIDS [J].
GUTOWSKY, HS ;
PAKE, GE .
JOURNAL OF CHEMICAL PHYSICS, 1950, 18 (02) :162-170
[9]   INDIVIDUAL SPECTRAL DENSITIES AND MOLECULAR-MOTION IN POLYCRYSTALLINE HEXAMETHYLBENZENE-D18 [J].
HOATSON, GL ;
VOLD, RL ;
TSE, TY .
JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (07) :4756-4765
[10]   A high-resolution 3D separated-local-field experiment by means of magic-angle turning [J].
Hu, JZ ;
Alderman, DW ;
Pugmire, RJ ;
Grant, DM .
JOURNAL OF MAGNETIC RESONANCE, 1997, 126 (01) :120-126