Soluble lanthanide-transition-metal clusters Ln36Co12 as effective molecular electrocatalysts for water oxidation

被引：15

作者：

Chen, Rong ^{[1
,2
]}

Chen, Chao-Long ^{[1
,2
]}

Du, Ming-Hao ^{[1
,2
]}

Wang, Xing ^{[1
,2
]}

Wang, Cheng ^{[1
,2
]}

Long, La-Sheng ^{[1
,2
]}

Kong, Xiang-Jian ^{[1
,2
]}

Zheng, Lan-Sun ^{[1
,2
]}

机构：

[1] Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chemist Solid Surfaces, Xiamen 361005, Peoples R China

[2] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 29期

基金：

中国国家自然科学基金;

关键词：

PHOTOSYSTEM-II; POLYOXOMETALATE; IDENTIFICATION; CATALYSTS; COMPLEX; CLOSER; CO4O4;

D O I：

10.1039/d0cc08132a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report for the first time soluble lanthanide-transition-metal clusters Ln(36)Co(12) (Ln = Eu, Gd and Dy) as effective homogeneous water oxidation electrocatalysts. The stable 48-metal Ln(36)Co(12) clusters show an effective water oxidation activity under acidic conditions because of the synergistic effect between lanthanide and transition metals in O-O bond formation.

引用

页码：3611 / 3614

页数：4

共 37 条

[1]

Barnett SM, 2012, NAT CHEM, V4, P498, DOI [10.1038/NCHEM.1350, 10.1038/nchem.1350]

[2] Integration of bio-inspired lanthanide-transition metal cluster and P-doped carbon nitride for efficient photocatalytic overall water splitting [J].

Chen, Rong ;

Zhuang, Gui-Lin ;

Wang, Zhi-Ye ;

Gao, Yi-Jing ;

Li, Zhe ;

Wang, Cheng ;

Zhou, Yang ;

Du, Ming-Hao ;

Zeng, Suyuan ;

Long, La-Sheng ;

Kong, Xiang-Jian ;

Zheng, Lan-Sun .

NATIONAL SCIENCE REVIEW, 2021, 8 (09)

[3] Recent Advances in First-Row Transition Metal Clusters for Photocatalytic Water Splitting [J].

Chen, Rong ;

Yan, Zhi-Hao ;

Kong, Xiang-Jian .

CHEMPHOTOCHEM, 2020, 4 (03) :157-167

[4] A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Separation and Magnetic Cooling Applications [J].

Chen, Wei-Peng ;

Liao, Pei-Qin ;

Yu, Youzhu ;

Zheng, Zhiping ;

Chen, Xiao-Ming ;

Zheng, Yan-Zhen .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (32) :9375-9379

[5] Development of Bioinspired Mn4O4-Cubane Water Oxidation Catalysts: Lessons from Photosynthesis [J].

Dismukes, G. Charles ;

Brimblecombe, Robin ;

Felton, Greg A. N. ;

Pryadun, Ruslan S. ;

Sheats, John E. ;

Spiccia, Leone ;

Swiegers, Gerhard F. .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (12) :1935-1943

[6] Fast Water Oxidation Using Iron [J].

Ellis, W. Chadwick ;

McDaniel, Neal D. ;

Bernhard, Stefan ;

Collins, Terrence J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (32) :10990-10991

[7] 3d-4f {Co3IILn(OR)4} Cubanes as Bio-lnspired Water Oxidation Catalysts [J].

Evangelisti, Fabio ;

More, Rene ;

Hodel, Florian ;

Luber, Sandra ;

Patzke, Greta Ricarda .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (34) :11076-11084

[8] Closer to Photosystem II: A Co4O4 Cubane Catalyst with Flexible Ligand Architecture [J].

Evangelisti, Fabio ;

Guettinger, Robin ;

More, Rene ;

Luber, Sandra ;

Patzke, Greta R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (50) :18734-18737

[9] Four 3d-4f heterometallic Ln45M7 clusters protected by mixed ligands [J].

Fan, Shen ;

Xu, Su-Hui ;

Zheng, Xiu-Ying ;

Yan, Zhi-Hao ;

Kong, Xiang-Jian ;

Long, La-Sheng ;

Zheng, Lan-Sun .

CRYSTENGCOMM, 2018, 20 (15) :2120-2125

[10] Electrocatalytic water oxidation studies of a tetranuclear Cu(ii) complex with cubane-like core Cu4(μ3-O)4 [J].

Gao, Wei-Song ;

Wang, Jin-Miao ;

Shi, Ning-Ning ;

Chen, Chang-Neng ;

Fan, Yu-Hua ;

Wang, Mei .

NEW JOURNAL OF CHEMISTRY, 2019, 43 (11) :4640-4647

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