Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation

被引：11

作者：

Pejic, Natasa ^{[1
]}

Kolar-Anic, Ljiljana ^{[2
]}

Maksimovic, Jelena ^{[2
]}

Jankovic, Marija ^{[3
]}

Vukojevic, Vladana ^{[4
]}

Anic, Slobodan ^{[2
]}

机构：

[1] Univ Belgrade, Dept Phys Chem & Instrumental Methods, Fac Pharm, Vojvode Stepe 450, Belgrade 11000, Serbia

[2] Univ Belgrade, Fac Phys Chem, Studentski Trg 12-16, Belgrade 11000, Serbia

[3] Univ Belgrade, Radiat & Environm Protect Dept, Inst Nucl Sci Vinca, Mihajla Petrovica Alasa 12-14,POB 522, Belgrade 11001, Serbia

[4] Karolinska Inst, Ctr Mol Med, Dept Clin Neurosci, CMM L8 01, S-17176 Stockholm, Sweden

来源：

REACTION KINETICS MECHANISMS AND CATALYSIS | 2016年 / 118卷 / 01期

关键词：

Nonlinear dynamics; Bifurcations; Bray-Liebhafsky oscillatory reaction; CSTR; LIMIT-CYCLE OSCILLATIONS; BELOUSOV-ZHABOTINSKII REACTION; PULSE PERTURBATION TECHNIQUE; INFINITE PERIOD; QUASI-PERIODICITY; MALONIC-ACID; OXALIC-ACID; EXCITABILITY; BEHAVIOR; SYSTEM;

D O I：

10.1007/s11144-016-0984-y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The temporal dynamics of the Bray-Liebhafsky reaction (iodate-based catalytic decomposition of hydrogen peroxide in an acidic aqueous solution) was experimentally characterized in a continuous stirred tank reactor by independently varying the temperature and the mixed inflow hydrogen peroxide concentration. When the temperature was the bifurcation parameter, the emergence/disappearance of oscillatory behavior via a supercritical Andronov-Hopf bifurcation was observed for different mixed inflow hydrogen peroxide concentrations. An increase in the mixed inflow hydrogen-peroxide concentration resulted in a shift of the bifurcation point towards higher values of temperature, but did not alter the bifurcation type.

引用

页码：15 / 26

页数：12

共 53 条

[1] Methods to determine activation energies for the two kinetic states of the oscillatory Bray-Liebhafsky reaction [J].

Anic, S ;

KolarAnic, L ;

Koros, E .

REACTION KINETICS AND CATALYSIS LETTERS, 1997, 61 (01) :111-116

[2]

[Anonymous], 1994, Nonlinear dynamics and chaos: with applications to physics, biology, chemistry, and engineering, DOI 9780738204536

[3] FROM QUASI-PERIODICITY TO CHAOS IN THE BELOUSOV-ZHABOTINSKII REACTION .1. EXPERIMENT [J].

ARGOUL, F ;

ARNEODO, A ;

RICHETTI, P ;

ROUX, JC .

JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (06) :3325-3338

[4] PERIOD LENGTHENING NEAR THE END OF OSCILLATIONS IN CHEMICAL-SYSTEMS [J].

BARELI, K ;

BRONS, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (18) :7170-7177

[5] Malonic acid concentration as a control parameter in the kinetic analysis of the Belousov-Zhabotinsky reaction under batch conditions [J].

Blagojevic, Slavica M. ;

Anic, Slobodan R. ;

Cupic, Zeljko D. ;

Pejic, Natasa D. ;

Kolar-Anic, Ljiljana Z. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (44) :6658-6664

[6] TRANSITIONS FROM BISTABILITY TO LIMIT-CYCLE OSCILLATIONS - THEORETICAL-ANALYSIS AND EXPERIMENTAL-EVIDENCE IN AN OPEN CHEMICAL-SYSTEM [J].

BOISSONADE, J ;

DEKEPPER, P .

JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (05) :501-506

[7] A periodic reaction in homogeneous solution and its relation to catalysis. [J].

Bray, WC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1921, 43 :1262-1267

[8]

BRAY WC, 1931, J AM CHEM SOC, V53, P38, DOI DOI 10.1021/JA01352A006

[9]

BRONS M, 1991, J PHYS CHEM-US, V95, P8706

[10] Oscillations of the Bray-Liebhafsky reaction at low flow rates in a continuous flow stirred tank reactor [J].

Buchholtz, FG ;

Broecker, S .

JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (09) :1556-1559

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