Versatile self-assembly of supramolecular block copolymers with ionic cluster junctions

被引：13

作者：

Cao, Xiao ^{[1
]}

Zhang, Liying ^{[1
]}

Xu, Tianyang ^{[1
]}

Zhang, Shilin ^{[1
]}

Zhang, Hao ^{[1
]}

Li, Haolong ^{[1
]}

Wu, Lixin ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

来源：

POLYMER CHEMISTRY | 2016年 / 7卷 / 19期

基金：

中国国家自然科学基金;

关键词：

HYBRID ASSEMBLIES; HEAD GROUPS; POLYOXOMETALATE; POLYMERS; MICELLES; VESICLES; WATER; POLYMERIZATION; NANOSTRUCTURE; AMPHIPHILES;

D O I：

10.1039/c6py00514d

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Clusto-supramolecular block copolymers are synthesized by using an anionic cluster [W6O19](2-) as an ionic junction to link two cationic terminated polystyrene chains. These polymers exhibit versatile self-assembly behaviours not only dependent on the molecular weight but also adaptive to the concentration and temperature.

引用

页码：3216 / 3220

页数：5

共 55 条

[1]

[Anonymous], CHEM SOC REV

[2] Cationic linear triphos, L[PhP(CH2CH2PPh2)2], alkyne complexes of molybdenum(II) and tungsten(II);: crystal structures of [WI(CO)-(L-P,P′,P")(η2-MeC2Me)]2[W6O19], [WI(CO)(L-P,P′,P")(η2-MeC2Me)][BPh4] and [MoBr2(O){Ph2P(CH2)2PPh(CH2)2POPh2-P,P′,O}] [J].

Baker, PK ;

Drew, MGB ;

Meehan, MM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (05) :765-771

[3] The Link that Lasts: A New Frontier in Supramolecular Block Copolymer Design [J].

Barner, Leonie ;

Barner-Kowollik, Christopher .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (40) :11612-11614

[4] Anionic vinyl polymerization -: 50 years after Michael!Szwarc [J].

Baskaran, Durairaj ;

Mueller, Axel H. E. .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (02) :173-219

[5] Supramolecular polymers [J].

Brunsveld, L ;

Folmer, BJB ;

Meijer, EW ;

Sijbesma, RP .

CHEMICAL REVIEWS, 2001, 101 (12) :4071-4097

[6] Micelles and Vesicles Formed by Polyoxometalate-Block Copolymer Composites [J].

Bu, Weifeng ;

Uchida, Sayaka ;

Mizuno, Noritaka .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (44) :8281-8284

[7] Polymerization-induced self-assembly of block copolymer nanoparticles via RAFT non-aqueous dispersion polymerization [J].

Derry, Matthew J. ;

Fielding, Lee A. ;

Armes, Steven P. .

PROGRESS IN POLYMER SCIENCE, 2016, 52 :1-18

[8] Block copolymers: controlling nanostructure to generate functional materials - synthesis, characterization, and engineering [J].

Epps, Thomas H., III ;

O'Reilly, Rachel K. .

CHEMICAL SCIENCE, 2016, 7 (03) :1674-1689

[9] Stimuli-responsive aqueous micelles from an ABC metallo-supramolecular triblock copolymer [J].

Gohy, JF ;

Lohmeijer, BGG ;

Varshney, SK ;

Décamps, B ;

Leroy, E ;

Boileau, S ;

Schubert, US .

MACROMOLECULES, 2002, 35 (26) :9748-9755

[10] Giant thermal tunability of the lamellar spacing in block-copolymer-like supramolecules formed from binary-end-functionalized polymer blends [J].

Huh, J ;

Park, HJ ;

Kim, KH ;

Park, C ;

Jo, WH .

ADVANCED MATERIALS, 2006, 18 (05) :624-+

← 1 2 3 4 5 6 →