When three is not a crowd: the first trinuclear complexes of N4-substituted-3,5-dipyridyl-1,2,4-triazole ligands, [FeII3(Rdpt)4(NCS)6]

被引:15
作者
Kitchen, Jonathan A. [1 ,2 ]
Jameson, Guy N. L. [1 ,2 ]
Milway, Victoria A. [1 ,2 ]
Tallon, Jeffery L. [3 ,4 ]
Brooker, Sally [1 ,2 ]
机构
[1] Univ Otago, Dept Chem, Dunedin 9054, New Zealand
[2] Univ Otago, MacDiarmid Inst Adv Mat & Nanotechnol, Dunedin 9054, New Zealand
[3] Ind Res Ltd, Lower Hutt, New Zealand
[4] MacDiarmid Inst Adv Mat & Nanotechnol, Lower Hutt, New Zealand
关键词
SPIN-CROSSOVER; IRON(II) COMPLEXES; FE(ABPT)(2)(NCX)(2) X; MAGNETIC-PROPERTIES; TRANSITION; SE;
D O I
10.1039/c0dt00716a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first examples of trinuclear complexes of any dipyridyltriazole, [Fe-3(II)(Rdpt)(4)(NCS)(6)], are, respectively: [HS-HS-HS] when Rdpt = phdpt and "[LS-HS-LS]" when Rdpt = ibdpt.
引用
收藏
页码:7637 / 7639
页数:3
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