When three is not a crowd: the first trinuclear complexes of N4-substituted-3,5-dipyridyl-1,2,4-triazole ligands, [FeII3(Rdpt)4(NCS)6]

被引：15

作者：

Kitchen, Jonathan A. ^{[1
,2
]}

Jameson, Guy N. L. ^{[1
,2
]}

Milway, Victoria A. ^{[1
,2
]}

Tallon, Jeffery L. ^{[3
,4
]}

Brooker, Sally ^{[1
,2
]}

机构：

[1] Univ Otago, Dept Chem, Dunedin 9054, New Zealand

[2] Univ Otago, MacDiarmid Inst Adv Mat & Nanotechnol, Dunedin 9054, New Zealand

[3] Ind Res Ltd, Lower Hutt, New Zealand

[4] MacDiarmid Inst Adv Mat & Nanotechnol, Lower Hutt, New Zealand

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 33期

关键词：

SPIN-CROSSOVER; IRON(II) COMPLEXES; FE(ABPT)(2)(NCX)(2) X; MAGNETIC-PROPERTIES; TRANSITION; SE;

D O I：

10.1039/c0dt00716a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first examples of trinuclear complexes of any dipyridyltriazole, [Fe-3(II)(Rdpt)(4)(NCS)(6)], are, respectively: [HS-HS-HS] when Rdpt = phdpt and "[LS-HS-LS]" when Rdpt = ibdpt.

引用

页码：7637 / 7639

页数：3

共 21 条

[1] Nano-magnetic materials: spin crossover compounds vs. single molecule magnets vs. single chain magnets [J].

Brooker, Sally ;

Kitchen, Jonathan A. .

DALTON TRANSACTIONS, 2009, (36) :7331-7340

[2]

Garcia Y, 2000, EUR J INORG CHEM, P1531

[3] Polymorphism and pressure driven thermal spin crossover phenomenon in [Fe(abpt)2(NCX)2] (X = S, and Se):: Synthesis, structure and magnetic properties [J].

Gaspar, AB ;

Muñoz, MC ;

Moliner, N ;

Ksenofontov, V ;

Levchenko, G ;

Gütlich, P ;

Real, JA .

MONATSHEFTE FUR CHEMIE, 2003, 134 (02) :285-294

[4]

HAASNOOT JG, 1996, 1 2 4 TRIAZOLES LIGA

[5] Iron(II)-1,2,4-triazole spin transition molecular materials [J].

Kahn, O ;

Codjovi, E .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1996, 354 (1706) :359-379

[6]

Kahn O, 1999, CHEM BRIT, V35, P24

[7]

KITCHEN JA, UNPUB

[8] High and Low Spin Mononuclear and Dinuclear Iron(II) Complexes of 4-Amino and 4-Pyrrolyl-3,5-di(2-pyridyl)-4H-1,2,4-triazoles [J].

Kitchen, Jonathan A. ;

Noble, Andy ;

Brandt, Carsten D. ;

Moubaraki, Boujemaa ;

Murray, Keith S. ;

Brooker, Sally .

INORGANIC CHEMISTRY, 2008, 47 (20) :9450-9458

[9] Spin crossover in iron(II) complexes of 3,5-di(2-pyridyl)-1,2,4-triazoles and 3,5-di(2-pyridyl)-1,2,4-triazolates [J].

Kitchen, Jonathan A. ;

Brooker, Sally .

COORDINATION CHEMISTRY REVIEWS, 2008, 252 (18-20) :2072-2092

[10] Room-temperature spin crossover and Langmuir-Blodgett film formation of an iron(II) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog [J].

Kitchen, Jonathan A. ;

White, Nicholas G. ;

Gandolfi, Claudio ;

Albrecht, Martin ;

Jameson, Guy N. L. ;

Tallon, Jeffery L. ;

Brooker, Sally .

CHEMICAL COMMUNICATIONS, 2010, 46 (35) :6464-6466

← 1 2 3 →