Simple synthesis and characterization of novel polyvinyl alcohol capped sodium selenite solid composite film (PVA: NaSe SCF) samples

被引:8
作者
Bouzidi, A. [1 ]
Jilani, W. [1 ,2 ]
AlAbdulaal, T. H. [3 ]
Jalalah, Mohammed [4 ,5 ]
Harraz, Farid A. [4 ,6 ]
Yahia, I. S. [3 ,7 ,8 ]
Ibrahim, Medhat A. [9 ,10 ]
Zahran, H. Y. [3 ,7 ,8 ]
机构
[1] Univ Sfax Tunisia, Fac Sci Sfax, Lab Mat Energy & Environm & Modeling LMEEM, BP 1171, Sfax 3038, Tunisia
[2] King Khalid Univ, Fac Sci Sci & Arts Dhahran Al Janoub, Dept Phys, POB 960-61421, Abha, Saudi Arabia
[3] King Khalid Univ, Fac Sci, Dept Phys, Lab Nanosmart Mat Sci & Technol LNSMST, POB 9004, Abha, Saudi Arabia
[4] Najran Univ, Promising Ctr Sensors & Elect Devices PCSED, Adv Mat & Nanores Ctr, POB 1988, Najran 11001, Saudi Arabia
[5] Najran Univ, Fac Engn, Dept Elect Engn, POB 1988, Najran 11001, Saudi Arabia
[6] Cent Met Res & Dev Inst CMRDI, Nanomat & Nanotechnol Dept, PO 87 Helwan, Cairo 11421, Egypt
[7] King Khalid Univ, Res Ctr Adv Mat Sci RCAMS, POB 9004, Abha 61413, Saudi Arabia
[8] Ain Shams Univ, Fac Educ, Nanosci Lab Environm & Biomed Applicat NLEBA, Dept Phys,Semicond Lab, Cairo 11757, Egypt
[9] British Univ Egypt BUE, Nanotechnol Res Ctr NTRC, Suez Desert Rd, Cairo 11837, Egypt
[10] Natl Res Ctr, Spect Dept, Mol Spect & Modeling Unit, 33 El Bohouth St, Giza 12622, Egypt
来源
JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES | 2022年 / 7卷 / 03期
关键词
Sodium selenite doped-PVA: NaSe SCF samples; Energy bandgaps; Urbach's energy; AC electric conductivity/dielectric properties; AC impedance and CUT-OFF laser filters; STRUCTURAL-PROPERTIES; DIELECTRIC-PROPERTIES; OPTICAL-PROPERTIES; ELECTRICAL-PROPERTIES; OXIDE NANOCOMPOSITE; POLYMER COMPOSITES; SPECTROSCOPY; CONDUCTIVITY; IMPEDANCE; AGENT;
D O I
10.1016/j.jsamd.2022.100458
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Microstructural, optical, AC dielectric impedance, and conductivity properties of pure PVA and PVA: NaSe SCF samples doped with various NaSe salt fillers were investigated. The XRD study confirmed the semicrystalline structure of the PoIVA:NaSe SCF samples which explicated the semi-crystalline nature of the pure PoIVA as a matrix. This is related to a strong intermolecular contact among PoIVA chains over intermolecular hydrogen connections. As NaSe salt fillers in the PoIVA matrix increased, bandgap energies decreased. The Urbach energy was also changed with the variation of Mo concentration. The AC dielectric properties were enhanced with the introduction of NaSe salt fillers. As the NaSe salt fillers increase, the DC electrical conductivity parameters decrease. The AC impedance parameters infer that the prepared sample is a potential dielectric candidate. The studied material can be used in electronic and optoelectronic applications, especially CUT-OFF laser filters. (C) 2022 Vietnam National University, Hanoi. Published by Elsevier B.V.
引用
收藏
页数:10
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