One-step controlled electrodeposition of iron-based binary metal organic nanocomposite

被引：22
作者：
Zhang, Birong [1 ,2 ]
Huang, Pin [1 ,2 ]
Chen, Jianxiong [1 ,2 ]
Dang, Xueping [1 ,2 ,3 ,4 ]
Hu, Yuling [3 ]
Ai, Youhong [1 ,2 ]
Zheng, Dongyun [4 ]
Chen, Huaixia [1 ,2 ]
机构：
[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China
[2] Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China
[3] Sun Yat Sen Univ, Sch Chem, Guangzhou 510275, Guangdong, Peoples R China
[4] Hubei Key Lab Med Informat Anal & Tumor Diag & Tr, Wuhan 430062, Peoples R China
来源：
APPLIED SURFACE SCIENCE | 2020年 / 504卷
基金：
国家重点研发计划;
关键词：
Metal organic materials (MOMs); Fe/Fe-BTC nanocomposite; Electrodeposition; Electrocatalysis; Adsorption; LIQUID-CHROMATOGRAPHIC SEPARATION; FACILE SYNTHESIS; CARBON-DIOXIDE; MIL-100; FE; FRAMEWORKS; RECOGNITION; PEROXIDE; STORAGE; FILMS; WATER;
D O I：
10.1016/j.apsusc.2019.144504
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A cauliflower-shaped Fe/Fe-BTC nanocomposite was prepared by one-step controlled cathodic electrodeposition method. The obtained Fe-BTC nanoscale film was characterized by scanning electron microscopy (SEM), energy-dispersive spectrometer (EDS), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectra (FT-IR), thermogravimetric analysis (TGA) and electrochemical measurements, indicating its morphology, structure and electrochemical activities varied with the applied cathodic potential. The electrodeposition process was investigated thoroughly and the electrosynthesis mechanism of the Fe/Fe-BTC nanocomposite was proposed. The Fe/Fe-BTC nanoscale film deposited at - 1.5 V exhibited the loosest morphology and best electrochemical activity, which showed the best application potential in electrocatalytic H2O2 reduction and adsorption of diethyl phthalate (DEP) and dibutyl phthalate (DBP). The iron-based binary metal organic materials were designable and could be applied in the field of electrocatalysis and extraction.
引用
收藏
页数：8
相关论文
共 41 条
  • [1] Bard A. J., 1980, ELECTROCHEMICAL METH, DOI [10.1021/ed060pA25.1, DOI 10.1021/ED060PA25.1]
  • [2] Understanding the Colloidal Stability of the Mesoporous MIL-100(Fe) Nanoparticles in Physiological Media
    Bellido, Elena
    Guillevic, Mazheva
    Hidalgo, Tania
    Santander-Ortega, Manuel J.
    Serre, Christian
    Horcajada, Patricia
    [J]. LANGMUIR, 2014, 30 (20) : 5911 - 5920
  • [3] HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC SEPARATION OF THE ISOMERS OF BUTYLATED HYDROXYANISOLE
    BERRIDGE, JC
    KENT, J
    NORCOTT, KM
    [J]. JOURNAL OF CHROMATOGRAPHY, 1984, 285 (02): : 389 - 391
  • [4] On the electrochemical deposition of metal-organic frameworks
    Campagnol, Nicolo
    Van Assche, Tom R. C.
    Li, Minyuan
    Stappers, Linda
    Dinca, Mircea
    Denayer, Joeri F. M.
    Binnemans, Koen
    De Vos, Dirk E.
    Fransaer, Jan
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (10) : 3914 - 3925
  • [5] High pressure, high temperature electrochemical synthesis of metal-organic frameworks: films of MIL-100 (Fe) and HKUST-1 in different morphologies
    Campagnol, Nicolo
    Van Assche, Tom
    Boudewijns, Tom
    Denayer, Joeri
    Binnemans, Koen
    De Vos, Dirk
    Fransaer, Jan
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (19) : 5827 - 5830
  • [6] H2 storage in isostructural UiO-67 and UiO-66 MOFs
    Chavan, Sachin
    Vitillo, Jenny G.
    Gianolio, Diego
    Zavorotynska, Olena
    Civalleri, Bartolomeo
    Jakobsen, Soren
    Nilsen, Merete H.
    Valenzano, Loredana
    Lamberti, Carlo
    Lillerud, Karl Petter
    Bordiga, Silvia
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (05) : 1614 - 1626
  • [7] Metal-Organic Frameworks with Functional Pores for Recognition of Small Molecules
    Chen, Banglin
    Xiang, Shengchang
    Qian, Guodong
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (08) : 1115 - 1124
  • [8] Hydrothermal synthesis and structural characterization of Zn(II)- and Cd(II)-pyridine-2,3-dicarboxylate 2D coordination polymers, {(NH4)2[M(μ-pydc)2]•2H2O}n
    Colak, Alper Tolga
    Pamuk, Gonul
    Yesilel, Okan Zafer
    Yuksel, Fatma
    [J]. SOLID STATE SCIENCES, 2011, 13 (12) : 2100 - 2104
  • [9] New opportunities for materials synthesis using mechanochemistry
    Friscic, Tomislav
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (36) : 7599 - 7605
  • [10] In vitro biocompatibility of mesoporous metal (III; Fe, Al, Cr) trimesate MOF nanocarriers
    Grall, Romain
    Hidalgo, Tania
    Delic, Jozo
    Garcia-Marquez, Alfonso
    Chevillard, Sylvie
    Horcajada, Patricia
    [J]. JOURNAL OF MATERIALS CHEMISTRY B, 2015, 3 (42) : 8279 - 8292
12345