Structural and redox features of La0.7Bi0.3Mn1-xCoxO3 nanoperovskites for ethane combustion and CO oxidation

被引：29

作者：

Gholizadeh, Ahmad ^{[1
]}

Malekzadeh, Azim ^{[2
]}

机构：

[1] Damghan Univ, Sch Phys, Damghan, Iran

[2] Damghan Univ, Sch Chem, Damghan, Iran

来源：

INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY | 2017年 / 14卷 / 03期

关键词：

C2H6 combustion and CO oxidation; manganite-cobaltite; nanoperovskites; structural phase transition; X-ray diffraction analysis; CATALYTIC-PROPERTIES; PEROVSKITES;

D O I：

10.1111/ijac.12650

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In this work, structural and catalytic properties of La0.7Bi0.3Mn1-xCoxO3 nanocatalysts with x=0.00, 0.25, 0.50, 0.75, and 1.00 prepared by citrate method are investigated. The structural characterization using X'Pert package and Fullprof program is an evidence for structural phase transition. The values of refined unit cell volume obtained from the Rietveld analysis show decreasing and increasing tendencies for values of x <= 0.5 and x>0.5, respectively. The catalytic performance tests of the catalysts show that the samples x=0.00 and 0.25 have lower temperature of CO oxidation and C2H6 combustion, respectively.

引用

收藏

页码：404 / 412

页数：9

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