Solid-State Nuclear Magnetic Resonance Spectroscopy: A Review of Modern Techniques and Applications for Inorganic Polymers

被引：24

作者：

Borisov, Alexey S. ^{[1
]}

Hazendonk, Paul ^{[1
]}

Hayes, Paul G. ^{[1
]}

机构：

[1] Univ Lethbridge, Dept Chem & Biochem, Lethbridge, AB T1K 3M4, Canada

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2010年 / 20卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

Solid-state nuclear magnetic resonance; MAS NMR; Spectroscopy; Inorganic polymers; Polysilanes; Polysiloxanes; Polysilazanes; Metal-containing polymers; ECHO DOUBLE-RESONANCE; C-N CERAMICS; SPIN-LATTICE RELAXATION; MULTIPLE-QUANTUM NMR; CROSS-POLARIZATION DYNAMICS; C-13 MAS NMR; CP/MAS NMR; MOLECULAR-DYNAMICS; CHAIN DYNAMICS; SEGMENTAL DYNAMICS;

D O I：

10.1007/s10904-010-9358-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The basic concepts of solid-state nuclear magnetic resonance (NMR) spectroscopy are explained in a clear and concise manner. First the reader is introduced to the principles of NMR spectroscopy and techniques that are most commonly utilized today. Next, an overview of advanced magic-angle spinning (MAS) NMR experiments, which can provide valuable insight into molecular structure, connectivity, dynamics, domains, and phases of inorganic polymers, is presented. The final chapter discusses the major classes of inorganic polymers, their properties and applications. It addresses their characterization including, if any, the role of solution and solid-state NMR spectroscopy, and provides prospective on potential applications of these techniques for the given class of material.

引用

页码：183 / 212

页数：30

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