New layered polymer [{Mn(H2O)3}2{Re6Se8(CN)6}] • 3.3H2O:: Synthesis and properties

被引：2

作者：

Naumov, NG ^{[1
]}

Artemkina, SB ^{[1
]}

Virovets, AV ^{[1
]}

Fedorov, VE ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Inst Inorgan Chem, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2004年 / 30卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1023/B:RUCO.0000047466.28548.48

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [{Mn(H2O)(3)}(2){Re6Se8(CN)(6)}](.)3.3H(2)O complex was produced on slow evaporation of an aqueous solution containing the salt of a cluster complex K4Re6Se8(CN)(6)(.)3.5H(2)O and a 23-fold excess of Mn2+. The cluster complexes [Re6Se8(CN)(6)](4-) are linked in a crystal into the charged coordination layers [{Mn(H2O)(3)}(4){Re6Se8(CN)(6)}(3)](2infinity)(4-) through the Mn2+ cations. The Mn2+ cations are coordinated in a layer by three cyano nitrogen atoms of the cluster complexes; the Mn-N bond lengths are 2.13(4) and 2.21(2) Angstrom. Each [Re6Se8(CN)(6)](4-) anion is bonded to three manganese cations Mn(l). The anions are bonded additionally to the Mn(2) cations disordered over two close positions.

引用

页码：792 / 799

页数：8

共 17 条

[1]

Artemkina SB, 2002, EUR J INORG CHEM, P1198

[2]

ARTEMKINA SB, 2003, THESIS NIKOLAEV I IN

[3] Cyano-bridged Re6Q8 (Q = S, Se) Cluster-Cobalt(II) framework materials:: Versatile solid chemical sensors [J].

Beauvais, LG ;

Shores, MP ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (12) :2763-2772

[4] Expanded Prussian blue analogues incorporating [Re6Se8(CN)6]3-/4- clusters:: Adjusting porosity via charge balance [J].

Bennett, MV ;

Beauvais, LG ;

Shores, MP ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :8022-8032

[5]

*ENR NON, 1998, CAD4 CADDAT

[6] SYNTHESIS AND CRYSTAL-STRUCTURE OF A HEXANUCLEAR RHENIUM CLUSTER COMPLEX CS3K[RE-6(MU(3)-S)(6) (MU(3)-TE0.66S0.34)2(CN)(6)] - CATIONIC CONTROL OVER ORIENTATION OF THE CLUSTER ANION [J].

MIRONOV, YV ;

VIROVETS, AV ;

FEDOROV, VE ;

PODBEREZSKAYA, NV ;

SHISHKIN, OV ;

STRUCHKOV, YT .

POLYHEDRON, 1995, 14 (20-21) :3171-3173

[7]

Naumov N. G., 1999, UKR KHIM ZH, V65, P21

[8] Facile transformation of isolated fragments to infinite chains in rhenium chalcocyanide clusters:: Synthesis and structure of (Pr4N)2M(H2O)5 [Re6X8(CN)6] • H2O and (Pr4N)2M(H2O)4 [Re6S8(CN)6] (X= S, Se; M= Mn, Ni) [J].

Naumov, NG ;

Artemkina, SB ;

Virovets, AV ;

Fedorov, VE .

JOURNAL OF SOLID STATE CHEMISTRY, 2000, 153 (02) :195-204

[9]

Naumov NG, 1998, ANGEW CHEM INT EDIT, V37, P1943, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1943::AID-ANIE1943>3.0.CO

[10]

2-Q

← 1 2 →