共 61 条
Solubility prediction of polycyclic aromatic hydrocarbons in non-aqueous solvent mixtures
被引:61
作者:
Jouyban, Abolghasem
[1
]
Shayanfar, All
[2
]
Acree, William E., Jr.
[3
]
机构:
[1] Tabriz Univ Med Sci, Drug Appl Res Ctr, Tabriz 51664, Iran
[2] Tabriz Univ Med Sci, Biotechnol Res Ctr, Tabriz 51664, Iran
[3] Univ N Texas, Dept Chem, Denton, TX 76203 USA
关键词:
Polycyclic aromatic hydrocarbons (PAHS);
Solubility;
Prediction;
Jouyban-Acree model;
MOBILE ORDER THEORY;
HYDROGEN-BONDED SOLUTIONS;
PLUS BUTANOL+1-PENTANOL MIXTURES;
THEORY STABILITY-CONSTANTS;
2 BINARY SOLVENTS;
298.15;
K;
THERMOCHEMICAL INVESTIGATIONS;
ACETONITRILE MIXTURES;
PYRENE SOLUBILITIES;
ORGANIC-SOLVENTS;
D O I:
10.1016/j.fluid.2010.02.014
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
This study is aimed at evaluating the applicability of the Jouyban-Acree model for predicting the solubility of polycyclic aromatic hydrocarbons (PAHs) in binary and ternary solvent mixtures at different temperatures by employing a large solubility data set. The solubility is predicted in solvent mixtures at different temperatures within an acceptable error range based on the experimental solubility data of PAHs in mono-solvents. The results reveal that the Jouyban-Acree model could be recommended for practical applications in chemical industries. (C) 2010 Elsevier B.V. All rights reserved.
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页码:47 / 58
页数:12
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