Kinetics modeling of a modified epoxy-amine formulation cured by thermal and microwave energy

被引:0
作者
Hedreul, C
Galy, J
Dupuy, J
Delmotte, M
More, C
机构
[1] Inst Natl Sci Appl Lyon, Mat Macromol Lab, CNRS, UMR 5627, F-69621 Villeurbanne, France
[2] ENSAM Paris, Lab Microstruct & Mecan Mat, CNRS, URA 1219, F-75013 Paris, France
关键词
kinetics; modeling; microwave; phase separation; epoxy-amine;
D O I
10.1002/(SICI)1097-4628(19980425)68:4<543::AID-APP5>3.3.CO;2-7
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The reaction kinetics of a rubber-modified epoxy formulation cured by microwave or thermal energy were investigated. Two phenomenological models were developed to predict the time and temperature dependence of the conversion for the neat and the modified systems. Good agreement was observed between the kinetic models and experimental results generated by chromatographic and calorimetric techniques. The same kinetic behavior was observed whatever the curing process (conventional or microwave heating). (C) 1998 John Wiley & Sons, Inc.
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页码:543 / 552
页数:10
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