V2O5/SBA-15 Nanocatalysts for the Selective Oxidation of 5-Hydroxymethylfurfural into 2,5-Diformylfuran

被引：1

作者：

Liao, Longfei ^{[1
]}

Liu, Ying ^{[1
]}

Wu, Shubin ^{[1
]}

机构：

[1] South China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

JOURNAL OF BIOBASED MATERIALS AND BIOENERGY | 2018年 / 12卷 / 04期

关键词：

Hydroxymethylfurfural; 2,5-Diformylfuran; V2O5/SBA-15; Aerobic Oxidation; AEROBIC OXIDATION; CATALYTIC PERFORMANCE; MESOPOROUS SILICA; CHEMICALS; BIOMASS; FORMALDEHYDE; VANADIUM; SOLVENT; PROPANE; METHANE;

D O I：

10.1166/jbmb.2018.1782

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A series of V2O5/SBA-15 catalysts with various loadings of 5, 10, 15 and 20% (by weight) V2O5 have been prepared by molecular designed dispersion (MDD) method and are characterized by N-2 adsorption-desorption, Fourier Transform-Raman spectroscopy (FT-Raman), transmission electron microscopy (TEM), low angle and wide-angle XRD, H-2 temperature programmed reduction (TPR), inductively coupled plasma-optical emission spectrometry (ICP-OES), and Ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis, DRS) techniques. Among V2O5/SBA-15 catalysts, the 10% V2O5/SBA-15 catalyst exhibited 88.6% 5-hydroxymethylfurfural (HMF) conversion with 57.9% yield of 2,5-diformylfuran (DFF) when molecular oxygen (0.28 MPa) and toluene were employed as green oxidant and organic solvent respectively at 110 degrees C. The remarkable performance of 10% V2O5/SBA-15 catalyst is owing to the isolated distribution of uniform sized nanovanadium species which are dispersed on the pore surfaces of the hexagonally well-ordered mesoporous material SBA-15 silica support.

引用

页码：321 / 329

页数：9

共 37 条

[1] Renewable resources based polymers: Synthesis and characterization of 2,5-diformylfuran-urea resin [J].

Amarasekara, Ananda S. ;

Green, Dalkeith ;

Williams, LaToya D. .

EUROPEAN POLYMER JOURNAL, 2009, 45 (02) :595-598

[2] Fe(III) complex anchored SBA-15 is a new heterogeneous catalyst for the cleavage of aliphatic C=C bond of styrene and its derivatives [J].

Anand, Narani ;

Reddy, Kannapu Hari Prasad ;

Swapna, Vinukonda ;

Rao, Kamaraju Seetha Rama ;

Burri, David Raju .

MICROPOROUS AND MESOPOROUS MATERIALS, 2011, 143 (01) :132-140

[3] Selective oxidation of HMF to DFF using Ru/γ-alumina catalyst in moderate boiling solvents toward industrial production [J].

Antonyraj, Churchil A. ;

Jeong, Jaewon ;

Kim, Bora ;

Shin, Seunghan ;

Kim, Sangyong ;

Lee, Kwan-Young ;

Cho, Jin Ku .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2013, 19 (03) :1056-1059

[4] Structure and catalytic properties of VOx/MCM materials for the partial oxidation of methane to formaldehyde [J].

Berndt, H ;

Martin, A ;

Brückner, A ;

Schreier, E ;

Müller, D ;

Kosslick, H ;

Wolf, GU ;

Lücke, B .

JOURNAL OF CATALYSIS, 2000, 191 (02) :384-400

[5]

Boykin David, 2004, EP, EP, Patent No. 0973750

[6] NMR CONFIRMATION OF STRAINED DEFECTS IN AMORPHOUS SILICA [J].

BRINKER, CJ ;

KIRKPATRICK, RJ ;

TALLANT, DR ;

BUNKER, BC ;

MONTEZ, B .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 99 (2-3) :418-428

[7] CuCl catalyst heterogenized on diamide immobilized SBA-15 for efficient oxidative carbonylation of methanol to dimethylcarbonate [J].

Cao, Y ;

Hu, JC ;

Yang, P ;

Dai, WL ;

Fan, KN .

CHEMICAL COMMUNICATIONS, 2003, (07) :908-909

[8] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].

Chheda, Juben N. ;

Huber, George W. ;

Dumesic, James A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183

[9]

Choudhary H., 2014, APPL CATAL B-ENVIRON, V162, P1

[10] Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts [J].

Climent, Maria J. ;

Corma, Avelino ;

Iborra, Sara .

GREEN CHEMISTRY, 2011, 13 (03) :520-540

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