Co(II), Ni(II), Cu(I) and Pd(II) complexes of p-anisaldene-thiosemicarbazone

被引：0

作者：

Borgh, Geetika ^{[1
]}

Baruah, Jayantajit ^{[1
]}

Kardong, Devid ^{[2
]}

机构：

[1] Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India

[2] Dibrugarh Univ, Dept Life Sci, Dibrugarh 786004, Assam, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2014年 / 53卷 / 12期

关键词：

Coordination chemistry; Antibacterial activity; Antifungal activity; Anticancer activity; Anisaldene; Thiosemicarbazone; Cobalt; Nickel; Copper; Palladium; METAL-COMPLEXES; ANTIBACTERIAL; DERIVATIVES; COPPER(II); NICKEL(II); ANTICANCER; ZINC(II); MN(II); COBALT; ASSAY;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of anisaldene-thiosemicarbazone (HL) with MCl2 center dot 6H(2)O (where M = Co(II) and Ni(II)), Cu(CH3COO)(2)center dot H2O and [Pd(COD)Cl-2] on stirring/refluxing affords six-coordinated [Co(L)(2)(HL)] (1) and four-coordinated [Ni(L)(2)] (2), [Cu(L)(HL)] (3) and [Pd(L)(COD)]Cl (4) complexes. All the complexes have been characterized by conductivity measurements, FTIR, UV-vis, ESI(+) mass, C-13 and H-1 NMR spectroscopy, TGA-DTA analysis, magnetic and cyclic voltammetry studies and screened in vitro for antimicrobial activity by the agar well method. The ligand and the Cu(I) complex have been tested for anticancer activity The Cu(I) complex exhibits quite good antifungal activity against R. solani and F. oxosporum ciceri, and also possesses better antiproliferative activity than the ligand against the cancer cells.

引用

页码：1520 / 1525

页数：6

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