Discovery of Kinetic Effect in a Valence Tautomeric Cobalt-Dioxolene Complex

被引：4
|
作者：
Sun, Xiao-Peng [1 ]
Tang, Zheng [2 ]
Li, Jiajia [1 ]
Ma, Pengtao [1 ]
Yao, Zi-Shuo [2 ]
Wang, Jingping [1 ]
Niu, Jingyang [1 ]
Tao, Jun [2 ]
机构：
[1] Henan Univ, Henan Key Lab Polyoxometalate Chem, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475004, Peoples R China
[2] Beijing Inst Technol, Key Lab Cluster Sci, Minist Educ, Sch Chem & Chem Engn, Liangxiang Campus, Beijing 102488, Peoples R China
来源：
INORGANIC CHEMISTRY | 2022年 / 61卷 / 10期
基金：
中国国家自然科学基金;
关键词：
LIGAND ELECTRON-TRANSFER; SPIN-CROSSOVER; ROOM-TEMPERATURE; MAGNETIC BISTABILITY; THERMAL HYSTERESIS; REDOX ACTIVITY; STATE; TRANSITION; SEMIQUINONE; MODULATION;
D O I：
10.1021/acs.inorgchem.1c03898
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two isostructural valence tautomeric (VT) complexes with different critical temperatures were prepared and fully investigated through a series of magnetic, structural, spectral, and differential scanning calorimetry evidence. The kinetic effect in the VT complex was observed for the first time through scan-rate-dependent studies and further validated by annealing tests
引用
收藏
页码：4240 / 4245
页数：6
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