Excited-State Dynamics of the 2-Hydroxypyridine-Ammonia Complex

被引:9
作者
Esboui, M. [3 ]
Jouvet, C. [1 ,2 ]
Dedonder, C. [1 ,2 ]
Ebata, T. [4 ]
机构
[1] Univ Paris 11, Photophys Mol Lab, CNRS, F-91405 Orsay, France
[2] Univ Paris 11, Ctr Laser, F-91405 Orsay, France
[3] Fac Sci Tunis, Dept Phys, Lab Spect Atom Mol & Applicat, Tunis 1060, Tunisia
[4] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima 7398526, Japan
关键词
H-ATOM-TRANSFER; PROTON-TRANSFER; HYDROGEN-TRANSFER; GAS-PHASE; INTERMOLECULAR VIBRATIONS; CLUSTERS; SPECTROSCOPY; AMMONIA; MODEL; 2-PYRIDONE;
D O I
10.1021/jp906652y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The excited-state lifetimes of different vibrational levels of the 2-hydroxypyridine-ammonia complex have been recorded with the picosecond pump probe technique These lifetimes decrease with increasing energy. The decrease of the lifetime is discussed based oil the possible enol keto isomerization computed using RI-CC2 methods
引用
收藏
页码:3060 / 3066
页数:7
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