Validation of lanthanide chiral shift reagents for determination of absolute configuration: Total synthesis of glisoprenin A

被引：28

作者：

Adams, CM ^{[1
]}

Ghosh, I ^{[1
]}

Kishi, Y ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 25期

关键词：

D O I：

10.1021/ol048059o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The complete stereostructure of the natural product (+)-glisoprenin A had been predicted via a novel application of chiral lanthanide shift reagents. Confirmation of the predicted stereostructure of (+)-glisoprenin A and validation of the chiral lanthanide shift approach have now been achieved through total synthesis.

引用

页码：4723 / 4726

页数：4

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