Rh(II)-Catalyzed Synthetic Strategy for Diverse and Functionalized Halonaphthalenyl Ethers and Esters from Diazo Compounds and Its Application to Polyaromatic Compounds

被引：13

作者：

Baral, Ek Raj ^{[1
]}

Lee, Yong Rok ^{[1
]}

Kim, Sung Hong ^{[2
]}

Wee, Young-Jung ^{[3
]}

机构：

[1] Yeungnam Univ, Sch Chem Engn, Kyongsan 712749, South Korea

[2] Korea Basic Sci Inst, Anal Res Div, Daegu Ctr, Taegu 702701, South Korea

[3] Yeungnam Univ, Dept Food Sci & Technol, Kyongsan 712749, South Korea

来源：

SYNTHESIS-STUTTGART | 2016年 / 48卷 / 04期

关键词：

diazo compounds; rhodium(II) catalyst; halonaphthalenyl ethers; halonaphthalenyl esters; polyaromatic compounds; ONE-POT SYNTHESIS; SUBSTITUTED ALPHA-HALOENONES; THERMAL CASCADE REACTIONS; DIAZODICARBONYL COMPOUNDS; REGIOSELECTIVE HALOGENATION; EFFICIENT SYNTHESIS; AROMATIC-COMPOUNDS; COUPLING REACTIONS; 3+2 CYCLOADDITION; BROMINATION;

D O I：

10.1055/s-0035-1561295

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and simple synthesis of various functionalized halonaphthalenyl ethers and esters in moderate to good yield was achieved via rhodium(II)-catalyzed reaction of readily available diazo compounds with benzyl halides or acid halides. This methodology has several advantages, such as ease of handling, mild reaction conditions, bromine- or chlorine-free route, and the use of an effective catalyst. The synthesized compounds were further converted into valuable polyaromatic compounds using the Suzuki reaction.

引用

页码：579 / 587

页数：9

共 60 条

[1] Synthesis of Diverse Indene Derivatives from 1-Diazonaphthalen-2(1H)-ones via Thermal Cascade Reactions [J].