Nano-Fe2O3-catalyzed direct borylation of arenes

被引：80

作者：

Yan, Guobing ^{[1
,2
,3
]}

Jiang, Yubo ^{[1
,2
,3
]}

Kuang, Chunxiang ^{[1
]}

Wang, Shuai ^{[2
,3
]}

Liu, Haichao ^{[2
,3
]}

Zhang, Yan ^{[2
,3
]}

Wang, Jianbo ^{[1
,2
,3
]}

机构：

[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China

[2] Peking Univ, Coll Chem, Minist Educ, BNLMS, Beijing 100871, Peoples R China

[3] Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 18期

关键词：

C-H BOND; IRIDIUM-CATALYZED BORYLATION; ONE-POT; DIRECT FUNCTIONALIZATION; DIRECT ARYLATION; ARYL HALIDES; N-ARYLATION; ACTIVATION; EFFICIENT; COMPLEXES;

D O I：

10.1039/b926945b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nano-Fe2O3-catalyzed borylation of arenes with diboron pinacol ester B(2)pin(2) has been found to give borylation products with selectivity controlled by electronic effects of substituents.

引用

页码：3170 / 3172

页数：3

共 72 条

[11] Steric and chelate directing effects in aromatic borylation [J].

Cho, JY ;

Iverson, CN ;

Smith, MR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (51) :12868-12869

[12] Iron-catalyzed N-arylations of Amides [J].

Correa, Arkaitz ;

Elmore, Simon ;

Bolm, Carsten .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (12) :3527-3529

[13] Iron-catalyzed S-arylation of thiols with aryl iodides [J].

Correa, Arkaitz ;

Carril, Monica ;

Bolm, Carsten .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (15) :2880-2883

[14] Iron-catalysed carbon-heteroatom and heteroatom-heteroatom bond forming processes [J].

Correa, Arkaitz ;

Mancheno, Olga Garcia ;

Bolm, Carsten .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (06) :1108-1117

[15] Iron-catalyzed N-arylation of nitrogen nucleophiles [J].

Correa, Arkaitz ;

Bolm, Carsten .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (46) :8862-8865

[16] Synthesis of Diarylamines Catalyzed by Iron Salts [J].

Correa, Arkaitz ;

Carril, Monica ;

Bolm, Carsten .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (35) :10919-10922

[17] Selective Ir-catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-2,6-bis(boronate), pyrene-2,7-bis(boronate) and perylene-2,5,8,11-tetra(boronate) esters [J].

Coventry, DN ;

Batsanov, AS ;

Goeta, AE ;

Howard, JAK ;

Marder, TB ;

Perutz, RN .

CHEMICAL COMMUNICATIONS, 2005, (16) :2172-2174

[18] Palladium- and Copper-Catalyzed Arylation of Carbon-Hydrogen Bonds [J].

Daugulis, Olafs ;

Do, Hien-Quang ;

Shabashov, Dmitry .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (08) :1074-1086

[19] Catalytic enantioselective C-H activation by means of metal-carbenoid-induced C-H insertion [J].

Davies, HML ;

Beckwith, REJ .

CHEMICAL REVIEWS, 2003, 103 (08) :2861-2903

[20] Coinage metal catalyzed C-H bond functionalization of hydrocarbons [J].

Diaz-Requejo, M. Mar ;

Perez, Pedro J. .

CHEMICAL REVIEWS, 2008, 108 (08) :3379-3394

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