First two-dimensional framework material constructed from bicapped Keggin structure clusters:: [Cu(en)2(H2O)] {[PMo8VIV6VIO42Cu(en)2][Cu0.5(en)]3}•5.5H2O

被引：26

作者：

Pan, CL

Xu, JQ ^{[1
]}

Chu, DQ

Li, GH

Lu, ZL

Yang, GD

机构：

[1] Jilin Univ, Coll Chem, Dept Chem, Changchun 130023, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

[3] Jilin Univ, Key Lab Supramol Struct & Spect, Changchun 130023, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 07期

基金：

中国国家自然科学基金;

关键词：

polyoxometalate; cluster compound; hydrothermal synthesis; crystal structure;

D O I：

10.1016/S1387-7003(03)00155-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction Of CuCl2 . 2H(2)O, Na2NMoO4.2H(2)O, NH4VO3, ethylenediamme (en) and H3PO4 yields a novel two-dimensional open-framework material. The extended structure consists of a network Of {PMo8V6O42 [Cu(en)2]}(5-) cages, with each cage connected to three other neighboring units via [Cu(en)(2)](2+) bridging groups. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：939 / 941

页数：3

共 19 条

[1]

[Anonymous], 1995, Transition Metal Oxides: An Introduction to Their Electronic Structure and Properties

[2]

Brown I.D., 1981, STRUCTURE BONDING CR, V2

[3] A bivanadyl capped, highly reduced Keggin polyanion, [PMo(V)(6)Mo(VI)(6)O(40)(V(IV)O)(2)](5-) [J].