Counterion-mediated weak and strong coupling electrostatic interaction between like-charged cylindrical dielectrics

被引:36
|
作者
Kanduc, Matej [1 ]
Naji, Ali [2 ,3 ]
Podgornik, Rudolf [1 ,4 ,5 ]
机构
[1] Jozef Stefan Inst, Dept Theoret Phys, SI-1000 Ljubljana, Slovenia
[2] Univ Cambridge, Ctr Math Sci, Dept Appl Math & Theoret Phys, Cambridge CB3 0WA, England
[3] Univ Sheffield, Dept Phys & Astron, Sheffield S3 7RH, S Yorkshire, England
[4] Univ Ljubljana, Dept Phys, Inst Biophys, SI-1000 Ljubljana, Slovenia
[5] Univ Ljubljana, Fac Med, Fac Math & Phys, Inst Biophys, SI-1000 Ljubljana, Slovenia
来源
JOURNAL OF CHEMICAL PHYSICS | 2010年 / 132卷 / 22期
关键词
DENSITY-FUNCTIONAL THEORY; DOUBLE-LAYER INTERACTIONS; POISSON-BOLTZMANN; POLYELECTROLYTE SOLUTIONS; ION DISTRIBUTION; BUNDLE FORMATION; FIELD-THEORY; ATTRACTION; DNA; FORCES;
D O I
10.1063/1.3430744
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We examine the effective counterion-mediated electrostatic interaction between two like-charged dielectric cylinders immersed in a continuous dielectric medium containing neutralizing mobile counterions. We focus on the effects of image charges induced as a result of the dielectric mismatch between the cylindrical cores and the surrounding dielectric medium and investigate the counterion-mediated electrostatic interaction between the cylinders in both limits of weak and strong electrostatic couplings (corresponding, e.g., to systems with monovalent and multivalent counterions, respectively). The results are compared with extensive Monte Carlo simulations exhibiting good agreement with the limiting weak and strong coupling results in their respective regime of validity. (C) 2010 American Institute of Physics. [doi:10.1063/1.3430744]
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页数:18
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