Crown ether-half-capped sodium ions as bridges in the formation of complex polymer, structure of [{(benzo-15-crown-5)Na}2Pd(i-mnt)2]n {i-mnt = [S2C=C(CN)2]2-}

被引：26

作者：

Long, DL ^{[1
]}

Chen, JT ^{[1
]}

Cui, Y ^{[1
]}

Huang, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

CHEMISTRY LETTERS | 1998年 / 02期

关键词：

D O I：

10.1246/cl.1998.171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Na2Pd(i-mnt)(2) and benzo-15-crown-5 leads to an unprecedented infinite chain-like [{(benzo-15-crown-5)Na}(2) Pd(i-mnt)(2)](n), in which the conjugated species Pd(i-mnt)(2) are linked by crown ether-half capp ed sodium ions via Na-NC bonds.

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页码：171 / 172

页数：2

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