Aqua(1H-benzimidazole-κN3)(pyridine2,6-dicarboxylato-κ3O2,N,O6)copper(II) 0.75-hydrate

被引:6
作者
Dong, Gui-Ying [2 ]
Fan, Li-Hua [2 ]
Yang, Li-Xia [2 ]
Khan, Islam Ullah [1 ]
机构
[1] Govt Coll Univ, Dept Chem, Mat Chem Lab, Lahore 54000, Pakistan
[2] Hebei Polytech Univ, Coll Chem Engn & Biotechnol, Tangshan 063009, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
D O I
10.1107/S160053681001353X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title complex, [Cu(C7H3NO4)(C7H6N2)(H2O)]center dot 0.75H(2)O, consists of discrete monomeric units. The Cu-II atom is coordinated by two carboxylate O atoms and the N atom from a dipicolinate unit and by an N atom from a benzimidazole ligand. The distorted square-pyramidal geometry is completed by a longer axial bond to the O atom of a water molecule. The molecular structure and packing are stabilized by classical O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, also including a disordered crystal water molecule.
引用
收藏
页码:M532 / U611
页数:8
相关论文
共 5 条
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