A classified and comparative review of Poly (2,5-dithienyl-N-substituted-pyrrole) derivatives for electrochromic applications

被引：25

作者：

Carbas, Buket Bezgin ^{[1
,2
]}

Ergun, Emine Gul Cansu ^{[1
,3
]}

机构：

[1] Karamanoglu Mehmetbey Univ, Dept Energy Syst Engn, Karaman, Turkey

[2] KaramanogluMehmetbey Univ, Conduct Polymers & Energy Applicat Lab, Karaman, Turkey

[3] Baskent Univ, Dept Elect & Elect Engn, Ankara, Turkey

来源：

EUROPEAN POLYMER JOURNAL | 2022年 / 175卷

关键词：

5-dithienylpyrrole; SNS; Electrochromism; Conjugated polymer; Electrochromic polymer; SOLUBLE CONDUCTING POLYMER; COLORATION EFFICIENCY; OPTICAL-PROPERTIES; SPECTROELECTROCHEMICAL PROPERTIES; ELECTROCHEMICAL SYNTHESIS; OPTOELECTRONIC PROPERTIES; FLUORESCENCE PROPERTIES; CONJUGATED POLYMERS; HIGH-CONTRAST; PYRROLE;

D O I：

10.1016/j.eurpolymj.2022.111363

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(2,5-dithienyl-1-substituted-pyrrole) derivatives are one of the important classes for conducting polymers, exhibiting versatile electrochromic property besides used material in a broad range of smart applications. This review offers an overview of various SNS derivatives, mostly for electrochromic applications. In this compilation, the designed, synthesized and electrochemically and optically characterized conducting polymers of SNS derivatives in the literature up to today have been classified and comparatively discussed. The polymers of the SNS derivatives collected here have been prepared mostly by electrochemical techniques. According to N-substitutions form pyrrole unit, P(SNS) derivatives were grouped into five sections: N- alkyl-, phenyl-, amine/amide, homo/heterocyclic-, and crosslinked substituted derivatives. Each section mainly includes the structure-property relationship and the comparison of the effect of substitutions on the electrochromic properties of the resulting polymers.

引用

页数：18

共 110 条

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