Catalytic engineering of carbon nanotube production

被引：39

作者：

Yu, ZX

Chen, D

Totdal, B

Zhao, TJ

Dai, YC

Yuan, WK

Holmen, A

机构：

[1] Norwegian Univ Sci & Technol, Dept Chem Engn, NTNU, N-7491 Trondheim, Norway

[2] Norwegian Univ Sci & Technol, Dept Phys, NTNU, N-7491 Trondheim, Norway

[3] E China Univ Sci & Technol, UNILAB, State Key Lab Chem React Engn, Shanghai 200237, Peoples R China

来源：

APPLIED CATALYSIS A-GENERAL | 2005年 / 279卷 / 1-2期

关键词：

space velocity metal loading; production rate; productivity; large-scale synthesis;

D O I：

10.1016/j.apcata.2004.10.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The impact of some engineering aspects such as space velocity, catalyst metal loading, hydrogen. and temperature on carbon nanotube (CNT) production rate, productivity, and morphology in carbon monoxide disproportionation has been studied. The morphology and quality of the CNTs produced were examined by high resolution transmission electron microscopy (TEM). It was found that space velocity and metal loading have significant effects on the production rate and CNT productivity. The presence of H-2 dramatically increased the productivity, but altered the CNT structure. The synthesis temperature also influenced the carbon productivity and structure. The results were interpreted according to the traditional model for CNT growth, and the implications for large-scale CNT production were suggested. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：223 / 233

页数：11

共 41 条

[1] Alstrup I, 1998, MATER CORROS, V49, P367, DOI 10.1002/(SICI)1521-4176(199805)49:5<367::AID-MACO367>3.0.CO
[2] 2-M
[3] Synergism of Co and Mo in the catalytic production of single-wall carbon nanotubes by decomposition of CO
Alvarez, WE
Kitiyanan, B
Borgna, A
Resasco, DE
[J]. CARBON, 2001, 39 (04) : 547 - 558
[4] Carbon nanotube-modified cantilevers for improved spatial resolution in electrostatic force microscopy
Arnason, SB
Rinzler, AG
Hudspeth, Q
Hebard, AF
[J]. APPLIED PHYSICS LETTERS, 1999, 75 (18) : 2842 - 2844
[5] Coprecipitated Ni-alumina and Ni-Cu-alumina catalysts of methane decomposition and carbon deposition .2. Evolution of the catalysts in reaction
Avdeeva, LB
Goncharova, OV
Kochubey, DI
Zaikovskii, VI
Plyasova, LM
Novgorodov, BN
Shaikhutdinov, SK
[J]. APPLIED CATALYSIS A-GENERAL, 1996, 141 (1-2) : 117 - 129
[6] Preparation, reduction and CO chemisorption properties of cyanide-derived NixFe/Al2O3 catalysts
Boellaard, E
van der Kraan, AM
Geus, JW
[J]. APPLIED CATALYSIS A-GENERAL, 2002, 224 (1-2) : 1 - 20
[7] MATERIALS SCIENCE - STRENGTH IN DISUNITY
CALVERT, P
[J]. NATURE, 1992, 357 (6377) : 365 - 366
[8] Chen D, 1999, STUD SURF SCI CATAL, V126, P473
[9] Molecular cloning and tissue-specific, developmental-stage-specific, and hormonal regulation of IGFBP3 gene in zebrafish
Chen, JY
Chen, JC
Huang, WT
Liu, CW
Hui, CF
Chen, TT
Wu, JL
[J]. MARINE BIOTECHNOLOGY, 2004, 6 (01) : 1 - 7
[10] Carbon nanotubes: Synthesis, integration, and properties
Dai, HJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (12) : 1035 - 1044

← 1 2 3 4 5 →