Sulfur-substituted perylene diimides: efficient tuning of LUMO levels and visible-light absorption via sulfur redox

被引：18
|
作者：
Zhou, Yongxin [1 ]
Xue, Bo [1 ]
Wu, Chenyu [2 ]
Chen, Siqi [1 ]
Liu, Hui [1 ]
Jiu, Tonggang [3 ]
Li, Zhibo [1 ]
Zhao, Yingjie [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Shandong Prov Educ Dept, Coll Polymer Sci & Engn, Key Lab Biobased Polymer Mat, Qingdao 266042, Shandong, Peoples R China
[2] Univ New South Wales, Sydney, NSW 2018, Australia
[3] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Shandong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 90期
关键词：
SEMICONDUCTORS; DESIGN;
D O I：
10.1039/c9cc07040k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of sulfide and sulfone substituted perylene diimides (PDIs) with different LUMO levels covering a range of 0.72 eV were synthesized through simple sulfur redox chemistry. The LUMO level of phenylsulfone substituted PDI reached a record-breaking -4.75 eV. In addition, the maximum emission ranged from 540 to 692 nm.
引用
收藏
页码：13570 / 13573
页数：4
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