A review on the role of proton exchange membrane on the performance of microbial fuel cell

被引:72
作者
Rahimnejad, Mostafa [1 ,2 ]
Bakeri, Gholamreza [1 ]
Ghasemi, Mostafa [3 ]
Zirepour, Alireza [1 ]
机构
[1] Babol Noshirvani Univ Technol, Fac Chem Engn, Biofuel & Renewable Energy Res Ctr, Babol Sar, Iran
[2] Babol Noshirvani Univ Technol, Adv Membrane & Biotechnol Res Ctr, Fac Chem Engn, Babol Sar, Iran
[3] Univ Kebangsaan Malaysia, Fuel Cell Inst, Bangi 43600, Selangor Darul, Malaysia
关键词
proton exchange membranes; microbial fuel cells; Nafion; coulombic efficiency; ELECTRICITY-GENERATION; POWER-GENERATION; MEDIATOR-LESS; CATHODE; ION; PARAMETERS; TRANSPORT; CATION; ANION; DENITRIFICATION;
D O I
10.1002/pat.3383
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Proton exchange membranes (PEMs) are the most frequently used separators in microbial fuel cells (MFCs). The role of proton transportation in MFC performance makes PEMs one of the most important components in the cell. The effect of PEMs in MFC performance is commonly determined according to generated power density and coulombic efficiency. Nafion is the commonly used membrane in MFCs, but there are still a number of problems associated with the use of Nafion including oxygen transfer rate, cation transport and accumulation rather than protons, membrane fouling and substrate loss. Moreover, additional problems can also be attributed to the effect of PEMs including internal resistance and pH change in MFCs. Recent developments in PEM performance are attributed to two categories including utilization of other types of membranes and improvements in Nafion by pre-treatment methods. Copyright (c) 2014 John Wiley & Sons, Ltd.
引用
收藏
页码:1426 / 1432
页数:7
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