Percolation phenomena in carbon black-filled polymeric concrete

被引:18
作者
Rejón, L
Rosas-Zavala, A
Porcayo-Calderon, J
Castaño, VM
机构
[1] Inst Invest Elect, Cuernavaca 62001, Morelos, Mexico
[2] Univ Nacl Autonoma Mexico, Inst Fis, Queretaro 76000, Queretaro, Mexico
关键词
D O I
10.1002/pen.11342
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Percolation in carbon black-filled polymeric concrete, is discussed based on the measured changes in electrical conductivity and morphology of the composite at different concentrations of carbon black. The percolation threshold ranged between 6 and 7 wt% (based on resin weight) of carbon black. Above this concentration, the filler particles formed agglomerates in contact with each other, suggesting that the conduction process is nearly ohmic in nature. A power law predicted by percolation theory described the behavior of the conductivity as a function of carbon black content. Microscopic analysis showed the presence of a continuous structure formed by the polyester resin and carbon black, in which silica particles were embedded.
引用
收藏
页码:2101 / 2104
页数:4
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