Microwave-assisted synthesis using ionic liquids

被引:129
作者
Martinez-Palou, Rafael [1 ]
机构
[1] Inst Mexicano Petr, Programa Ingn Mol, Mexico City 07730, DF, Mexico
关键词
Ionic liquids; Microwave; Organic synthesis; Polymer synthesis; Materials synthesis; DIELS-ALDER REACTIONS; RING-OPENING POLYMERIZATION; OPTICALLY-ACTIVE POLYAMIDES; METAL-ORGANIC FRAMEWORKS; BAYLIS-HILLMAN REACTION; SOLVENT-FREE SYNTHESIS; ONE-POT SYNTHESIS; COMBINATORIAL CHEMISTRY; IONOTHERMAL SYNTHESIS; MICHAEL ADDITION;
D O I
10.1007/s11030-009-9159-3
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The research and application of green chemistry principles have led to the development of cleaner processes. In this sense, during the present century an ever-growing number of studies have been published describing the use of ionic liquids (ILs) as solvents, catalysts, or templates to develop more environmentally friendly and efficient chemical transformations for their use in both academia and industry. The conjugation of ILs and microwave irradiation as a non-conventional heating source has shown evident advantages when compared to conventional synthetic procedures for the generation of fast, efficient, and environmental friendly synthetic methodologies. This review focuses on the advances in the use of ILs in organic, polymers and materials syntheses under MW irradiation conditions.
引用
收藏
页码:3 / 25
页数:23
相关论文
共 185 条
[1]   Regioselective Heck reaction of N-vinylphthalimide:: A general strategy for the synthesis of (E)-N-Styrylphthalimides and phenethylamines [J].
Alacid, Emilio ;
Najera, Carmen .
ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (09) :1316-1322
[2]   Reproducibility across microwave instruments:: First example of genuine parallel scale up of compounds under microwave irradiation [J].
Alcázar, J ;
Diels, G ;
Schoentjes, B .
QSAR & COMBINATORIAL SCIENCE, 2004, 23 (10) :906-910
[3]  
Angrish C, 2005, INDIAN J CHEM B, V44, P1515
[4]   Acidic task-specific ionic liquid as catalyst of microwave-assisted solvent-free Biginelli reaction [J].
Arfan, A. ;
Paquin, L. ;
Bazureau, J. P. .
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2007, 43 (07) :1058-1064
[5]   Efficient combination of recyclable task specific ionic liquid and microwave dielectric heating for the synthesis of lipophilic esters [J].
Arfan, A ;
Bazureau, JP .
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2005, 9 (06) :743-748
[6]  
Berthold H, 2002, SYNTHESIS-STUTTGART, P1607
[7]   Microwave-assisted synthesis of camphor-derived chiral imidazolium ionic liquids and their application in diastereoselective Diels-Alder reaction [J].
Bica, Katharina ;
Gmeiner, Guenter ;
Reichel, Christian ;
Lendl, Bernhard ;
Gaertner, Peter .
SYNTHESIS-STUTTGART, 2007, 9 (09) :1333-1338
[8]   Out of the oil bath and into the oven - microwave-assisted combinatorial chemistry heats up [J].
Blackwell, HE .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (08) :1251-1255
[9]   Application of microwave irradiation to phase-transfer catalyzed reactions [J].
Bogdal, Dariusz ;
Loupy, Andre .
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2008, 12 (04) :710-722
[10]   Environmentally benign solvent systems: Toward a greener [4+2] cycloaddition process [J].
Brummond, K. M. ;
Wach, C. K. .
MINI-REVIEWS IN ORGANIC CHEMISTRY, 2007, 4 (01) :89-103