On metallocene-containing macromolecules and their applications

被引:20
|
作者
Gu, Haibin [1 ]
Ciganda, Roberto [2 ,3 ]
Gatard, Sylvain [2 ]
Lu, Feng [2 ]
Zhao, Pengxiang [4 ]
Ruiz, Jaime [2 ]
Astruc, Didier [2 ]
机构
[1] Sichuan Univ, Key Lab Leather Chem & Engn, Minist Educ, Chengdu 610065, Peoples R China
[2] Univ Bordeaux, ISM, UMR CNRS 5255, F-33405 Talence, France
[3] Univ Basque Country, Fac Quim San Sebastian, Apdo 1072, San Sebastian 20080, Spain
[4] Sci & Technol Surface Phys & Chem Lab, POB 718-35, Mianyang 621907, Sichuan, Peoples R China
基金
美国国家科学基金会;
关键词
Ferrocene; Cobalticinium; ROMP copolymer; Dendrimer; Redox activity; ORGANOMETALLIC ELECTRON-RESERVOIRS; LIVING RADICAL POLYMERIZATION; RING-OPENING POLYMERIZATION; WALLED CARBON NANOTUBES; METATHESIS POLYMERIZATION; ROMP SYNTHESIS; THIN-FILMS; STRAINED METALLOCENOPHANES; FERROCENYL DENDRIMERS; TRANSFER CHEMISTRY;
D O I
10.1016/j.jorganchem.2016.04.016
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A remarkable property of metallocenes, in particular those of the late first-row transition metals, is their redox function including the stability of two or several oxidation states. Recently our groups have introduced these compounds into precise dendrimers and polymers in view of sensing and catalytic applications. This short overview essentially focuses on the synthetic aspects and applications of our research conducted in this area. (C) 2016 Published by Elsevier B.V.
引用
收藏
页码:95 / 102
页数:8
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