Synthesis and Crystal Structure of a Heterometallic Chain Coordination Polymer: {[Ni2Mn2L2(CH3CH2OH)(H2O)]•CH3OH•2H2O}n

被引：0

作者：

Li Fu-An ^{[1
,2
]}

Wang Shou-Bin ^{[1
]}

Tao Ruo-Jie ^{[1
]}

机构：

[1] Henan Univ, Coll Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475001, Peoples R China

[2] Pingdingshan Univ, Coll Chem & Chem Engn, Pingdingshan 467000, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 29卷 / 01期

关键词：

nickel; manganese; coordination polymer; crystal structure; MAGNETIC-PROPERTIES; TETRANUCLEAR COMPLEXES; HEXAFLUOROACETYLACETONE; ARCHITECTURES; ANISOTROPY; OXIDATION; HHFAC;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A chain-like coordination polymer with the chemical formula of {[Ni2Mn2L2(CH3CH2OH)-(H2O)]center dot CH3OH center dot 2H(2)O}(n) has been synthesized by the. assembly reaction of K2NiL center dot H2O and Mn(OAC)(2)center dot 4H(2)O with a 1:1 mole ratio in methanol, where OAC(-) = CH3COO- and H4L = 2-hydroxy-3-[(E)-({2-[(2-hydroxybenzoyl)imino] ethyl}imino)methyl]benzoic acid. The crystal structure was determined by single-crystal X-ray diffraction analysis. It belongs to the triclinic system, space group P (1) over bar, with a = 9.9464(8), b = 13.4718(11), c = 14.3877(12) angstrom, alpha = 87.1930(10), beta = 85.4280(10), gamma = 74.6470(10)degrees, V = 1852.4(3) angstrom(3), Z = 2, D-c = 1.807 g/cm(3), M-r = 1008.03, lambda(MoK alpha) = 0.71073 angstrom, mu(MoK alpha) = 1.794 mm(-1), F(000) = 1032, R = 0.0527 and wR = 0.1284 (I > 2 sigma(I)). The compound exhibits a chain-like structure formed by dissymmetrical tetranuclear units.

引用

页码：63 / 68

页数：6

共 19 条

[1] AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].

BLESSING, RH .

ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38

[2] Proof of structure of 6-chloro-8-chloromethyl-1,3-benzodioxane by oxidation [J].

Buehler, CA ;

Bass, BC ;

Darling, RB ;

Lubs, ME .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :890-894

[3]

GATTESCHI D, NATO ASI SERIES E, V198

[4]

Han QX, 2009, CHINESE J STRUC CHEM, V28, P25

[5] SYMMETRY OF THE MAGNETIC ORBITALS AND EXCHANGE INTERACTION IN CUIIFEIII AND CUIICRIII HETEROBINUCLEAR COMPLEXES - CRYSTAL-STRUCTURE OF CUFE[(FSA)2EN]CL(H2O)(CH3OH).CH3OH [J].

JOURNAUX, Y ;

KAHN, O ;

ZAREMBOWITCH, J ;

GALY, J ;

JAUD, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (26) :7585-7591

[6]

KAHN O, 1996, NATO ASI SERIES C, V484

[7] Nature of copper(II)-lanthanide(III) magnetic interactions and generation of a large magnetic moment with magnetic anisotropy of 3d-4f cyclic cylindrical tetranuclear complexes [CuIILLnIII(hfaC)2]2, (H3L=1-(2-hydroxybenzamido)-2-(2-hydroxy-3-methoxybenzylideneamino)ethane and Hhfac = hexafluoroacetylacetone, LnIII = Eu, Gd, Tb, Dy) [J].

Kido, T ;

Ikuta, Y ;

Sunatsuki, Y ;

Ogawa, Y ;

Matsumoto, N .

INORGANIC CHEMISTRY, 2003, 42 (02) :398-408

[8] Self-assembly of a Cu(II)-Ba(II) 2D coordination polymer containing decanuclear 28-membered metallocycles [J].

Liu, WL ;

Zou, Y ;

Lu, CS ;

Ni, CL ;

Dang, DB ;

Li, YZ ;

Meng, QJ .

INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (03) :434-436

[9] Synthesis and magnetic properties of heterometal cyclic tetranuclear complexes [CuIILMII(hfac)]2 (MII = Zn, Cu, Ni, Co, Fe, Mn; H3L=1-(2-hydroxybenzamido)-2-((2-hydroxy-3-methoxybenzylidene)amino)ethane; Hhfac = hexafluoroacetylacetone) [J].

Osa, S ;

Sunatsuki, Y ;

Yamamoto, Y ;

Nakamura, M ;

Shimamoto, T ;

Matsumoto, N ;

Re, N .

INORGANIC CHEMISTRY, 2003, 42 (18) :5507-5512

[10] A tetranuclear 3d-4f single molecule magnet:: [CuIILTbIII(hfac)2]2 [J].

Osa, S ;

Kido, T ;

Matsumoto, N ;

Re, N ;

Pochaba, A ;

Mrozinski, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (02) :420-421

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