Copper-Catalyzed Electrophilic Arylation of Isatoic Anhydride with Diaryliodonium Salts for Synthesis of N-Phenylated Isatoic Anhydrides

被引：1
|
作者：
Wu, Xi-Xi [1 ,2 ]
He, Yonghui [1 ,2 ]
Zhao, Xiao-Jing [1 ,2 ]
Li, Ganpeng [1 ,2 ]
机构：
[1] Yunnan Minzu Univ, Sch Ethn Med, Key Lab Chem Ethn Med Resources, State Ethn Affairs Commiss, Kunming 650500, Yunnan, Peoples R China
[2] Yunnan Minzu Univ, Sch Ethn Med, State Ethn Affairs Commiss, Minist Educ,Key Lab Nat Prod Synthet Biol Ethn Me, Kunming 650500, Yunnan, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 11卷 / 07期
关键词：
copper-catalyzed; diaryliodonium salts; electrophilic arylation; mild conditions; N-Phenylated isatoic anhydrides; C-H AMINATION; O-LODOANILINES; CHEMISTRY; DERIVATIVES; QUINAZOLINONES; CARBONYLATION; ACCESS; ROUTE; BONDS; SITE;
D O I：
10.1002/ajoc.202200155
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A copper-catalyzed N-arylation of various isatoic anhydrides with diaryliodonium salts was developed by using inexpensive CuI as the catalyst under mild conditions. The method provides diverse N-Phenylated isatoic anhydrides in high yields (up to 97%). The mechanism of the N-arylation reaction is proposed to involve an electrophilic addition process.
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页数：5
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