Copper-Catalyzed Electrophilic Arylation of Isatoic Anhydride with Diaryliodonium Salts for Synthesis of N-Phenylated Isatoic Anhydrides

被引：1

作者：

Wu, Xi-Xi ^{[1
,2
]}

He, Yonghui ^{[1
,2
]}

Zhao, Xiao-Jing ^{[1
,2
]}

Li, Ganpeng ^{[1
,2
]}

机构：

[1] Yunnan Minzu Univ, Sch Ethn Med, Key Lab Chem Ethn Med Resources, State Ethn Affairs Commiss, Kunming 650500, Yunnan, Peoples R China

[2] Yunnan Minzu Univ, Sch Ethn Med, State Ethn Affairs Commiss, Minist Educ,Key Lab Nat Prod Synthet Biol Ethn Me, Kunming 650500, Yunnan, Peoples R China

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 11卷 / 07期

关键词：

copper-catalyzed; diaryliodonium salts; electrophilic arylation; mild conditions; N-Phenylated isatoic anhydrides; C-H AMINATION; O-LODOANILINES; CHEMISTRY; DERIVATIVES; QUINAZOLINONES; CARBONYLATION; ACCESS; ROUTE; BONDS; SITE;

D O I：

10.1002/ajoc.202200155

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A copper-catalyzed N-arylation of various isatoic anhydrides with diaryliodonium salts was developed by using inexpensive CuI as the catalyst under mild conditions. The method provides diverse N-Phenylated isatoic anhydrides in high yields (up to 97%). The mechanism of the N-arylation reaction is proposed to involve an electrophilic addition process.

引用

页数：5

共 49 条

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