Octahedral aqua fluoride rhenium cluster complexes K[Re6S8F3(H2O)3]•7H2O, H3O[Re6Se8F3(H2O)3]•7H2O and [Re6Q8F2(H2O)4]•12H2O (Q = S, Se):: Synthesis and structure

被引：12
作者：
Mironov, Yuri V.
Yarovoi, Spartak S.
Naumov, Dmitrii Y.
Simon, Arndt
Fedorov, Vladimir E.
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Max Planck Inst Festkorperforsch, D-707569 Stuttgart, Germany
来源：
INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
rhenium octahedral clusters; aqua fluoride complexes; synthesis; crystal structure;
D O I：
10.1016/j.ica.2007.02.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four new octahedral cluster complexes-K[Re6S8F3(H2O)(3)]center dot 7H(2)O (1), H3O[Re6Se8F3(H2O)(3)]center dot-7H(2)O (2) and [Re(6)Q(8)F(2)(H2O)(4)]center dot 12H(2)O (Q=S (3), Se (4)), have been synthesized using the reaction of rhenium chalcobromide complexes K-4[Re6S8Br6]center dot 2H(2)O and Cs-3[Re6Se8Br6]center dot H2O with molten KHF2 and further crystallization form aqueous solutions under different conditions. All compounds synthesized were characterized by X-ray single-crystal diffraction, chemical analysis, and IR spectra. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：2953 / 2957
页数：5
相关论文
共 21 条
  • [1] Synthesis of the first sulfido-bridged octahedral rhenium(III) aqua ion [Re6S8(H2O)6]2+
    Fedin, VP
    Virovets, AA
    Sykes, AG
    [J]. INORGANICA CHIMICA ACTA, 1998, 271 (1-2) : 228 - 230
  • [2] Chemistry of hexanuclear rhenium chalcohalide clusters
    Gabriel, JCP
    Boubekeur, K
    Uriel, S
    Batail, P
    [J]. CHEMICAL REVIEWS, 2001, 101 (07) : 2037 - 2066
  • [3] Octahedral rhenium cluster complexes with organic ligands:: Synthesis, structure and properties of [Re6Q8(3,5-Me2PzH)6]Br2•2(3,5-Me2PzH) (Q=S, Se)
    Mironov, YV
    Brylev, KA
    Shestopalov, MA
    Yarovoi, SS
    Fedorov, VE
    Spies, H
    Pietzsch, HJ
    Stephan, H
    Geipel, G
    Bernhard, G
    Kraus, W
    [J]. INORGANICA CHIMICA ACTA, 2006, 359 (04) : 1129 - 1134
  • [4] Mironov YV, 2005, EUR J INORG CHEM, P2476
  • [5] [Re6Q7O(3,5-Me2PzH)6]Br2•3,5-Me2PzH (Q = S, Se) -: New octahedral rhenium cluster complexes with organic ligands:: Original synthetic approach and unexpected ligand exchange in the cluster core
    Mironov, YV
    Shestopalov, MA
    Brylev, KA
    Yarovoi, SS
    Romanenko, GV
    Fedorov, VE
    Spies, H
    Pietzsch, HJ
    Stephan, H
    Geipel, G
    Bernhard, G
    Kraus, W
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (04) : 657 - 661
  • [6] First example of the cluster ammine complex [Re6Se7Br(NH3)6]3+:: synthesis and structure of the [Re6Se7Br(NH3)6][Re6Se7BrBr6] • 12H2O salt
    Mironov, YV
    Naumov, NG
    Yarovoi, SS
    Cordier, S
    Perrin, C
    Fedorov, VE
    [J]. RUSSIAN CHEMICAL BULLETIN, 2002, 51 (10) : 1919 - 1923
  • [7] Tellurium-continuing rhenium cluster complexes
    Mironov, YV
    Fedorov, VE
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 40 (06) : 959 - 974
  • [8] The new inorganic ligands TeCl2 and TeBr2: Syntheses and crystal structures of Re6Te6Cl6(TeCl2)(2) and [Re6Te8(TeBr2)(6)]Br-2
    Mironov, YV
    Pell, MA
    Ibers, JA
    [J]. INORGANIC CHEMISTRY, 1996, 35 (10) : 2709 - 2710
  • [9] Octahedral rhenium(III) chalcocyanide cluster anions: Synthesis, structure, and solid state design
    Naumov, NG
    Virovets, AV
    Fedorov, VE
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 41 (03) : 499 - 520
  • [10] Multielectron donors based on TTF-phosphine and ferrocene-phosphine hybrid complexes of a hexarhenium(III) octahedral cluster core
    Perruchas, S
    Avarvari, N
    Rondeau, D
    Levillain, E
    Batail, P
    [J]. INORGANIC CHEMISTRY, 2005, 44 (10) : 3459 - 3465
123