Breathing-induced new phase transition in an MIL-53(Al)-NH2 metal-organic framework under high methane pressures

被引：57

作者：

Bolinois, Linius ^{[1
]}

Kundu, Tanay ^{[1
]}

Wang, Xuerui ^{[1
]}

Wang, Yuxiang ^{[1
]}

Hu, Zhigang ^{[1
]}

Koh, Kenny ^{[1
]}

Zhao, Dan ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem & Biomol Engn, 4 Engn Dr 4, Singapore 117585, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 58期

关键词：

NATURAL-GAS; POROUS MATERIALS; CO2; ADSORPTION; STORAGE; MIL-53; SEPARATION; BEHAVIOR; FUNCTIONALIZATION; SORPTION;

D O I：

10.1039/c7cc02743e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The high pressure methane sorption tests on a flexible metal-organic framework [MIL-53(Al)-NH2] reveal a new phase transition to a large pore (lp) phase above 45 bar. The mixed-ligand strategy and pressure cycling tests are suggested to reduce the pressure requirement of such a phase transition for applications in natural gas storage.

引用

页码：8118 / 8121

页数：4

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