Diazabutadiene complexes of selenium as Se2+ transfer reagents

被引：25

作者：

Dutton, Jason L. ^{[1
]}

Battista, Taylor L. ^{[1
]}

Sgro, Michael J. ^{[1
]}

Ragogna, Paul J. ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON, Canada

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 07期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

OXIDATION-STATE; DOUBLE-BOND; CARBENE; ACTIVATION; DICATION; LIGANDS; CATIONS; ANALOGS; ALLENE; P-4;

D O I：

10.1039/b917841d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkyl and aryl substituted diazabutadiene ligands are shown to support a highly electrophilic "Se2+" synthon, which can be utilized in ligand exchange reactions to generate Se centred dicationic coordination complexes.

引用

页码：1041 / 1043

页数：3

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