Conversion of actual flue gas CO2 via cycloaddition to propylene oxide catalyzed by a single-site, recyclable zirconium catalyst

被引：62

作者：

Kelly, Michael J. ^{[1
]}

Barthel, Alexander ^{[1
]}

Maheu, Clement ^{[1
]}

Sodpiban, Ounjit ^{[2
]}

Dega, Frank-Blondel ^{[1
]}

Vummaleti, Sai V. C. ^{[1
]}

Abou-Hamad, Edy ^{[1
]}

Pelletier, Jeremie D. A. ^{[1
]}

Cavallo, Luigi ^{[1
]}

D'Elia, Valerio ^{[1
,2
]}

Basset, Jean-Marie ^{[1
]}

机构：

[1] King Abdullah Univ Sci & Technol, Kaust Catalysis Ctr, Thuwal 239556900, Saudi Arabia

[2] Vidyasirimedhi Inst Sci & Technol VISTEC, Sch Mol Sci & Engn, Dept Mat Sci & Engn, Wang Chan 21210, Thailand

来源：

JOURNAL OF CO2 UTILIZATION | 2017年 / 20卷

关键词：

CO2; conversion; Flue gas; Heterogeneous catalysis; Zirconium; Propylene carbonate; SURFACE ORGANOMETALLIC CHEMISTRY; CYCLIC CARBONATE SYNTHESIS; SOLID-STATE NMR; HIGHLY EFFICIENT; HETEROGENEOUS CATALYSTS; ORGANIC CARBONATES; SILICA; EPOXIDES; DIOXIDE; METATHESIS;

D O I：

10.1016/j.jcou.2017.05.020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A reusable zirconium-based catalyst for the cycloaddition of CO2 to propylene oxide (PO) was prepared by the surface organometallic chemistry (SOMC) methodology. Accordingly, well-defined amounts of the ZrCl4.(OEt2)(2) precursor were grafted on the surface of silica dehydroxylated at 700 degrees C (SiO2-700) and at 200 degrees C (SiO2-200) in order to afford surface coordination compounds with different podality and chemical environment. The identity of the surface complexes was thoroughly investigated by FT-IR, elemental microanalysis and solid state NMR and applied as a recoverable and reusable heterogeneous catalyst for the title reaction using pure CO2 and flue gas samples from a cement factory. The observed catalytic activity for the isolated zirconium complexes is rationalized by means of systematic DFT calculations.

引用

页码：243 / 252

页数：10

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