EFFECT OF ULTRASONIC TREATMENT ON THE PROPERTIES OF PYROPHYLLITE AND THERMODYNAMIC AND KINETIC REGULARITIES OF ITS INTERCALATION WITH LITHIUM

被引：1

作者：

Balaban, O. V. ^{[1
]}

Hryhorchak, I. I. ^{[1
]}

Kondyr, A. I. ^{[1
]}

机构：

[1] Lvivska Politekhn Natl Univ, Lvov, Ukraine

来源：

MATERIALS SCIENCE | 2014年 / 50卷 / 01期

基金：

美国国家科学基金会;

关键词：

pyrophyllite; layered structure; ultrasonic treatment; intercalation; Gibbs energy; Nyquist diagram; diffusion coefficient;

D O I：

10.1007/s11003-014-9698-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We study the influence of the ultrasonic treatment of pyrophyllite in different media on its structure and charge transfer and analyze the dependences of changes in the Gibbs free energy, resistance to charge transfer, and capacitance of the Helmholtz layer caused by the acoustic action on the amount of "guest" lithium x. It is shown that abnormally high diffusion coefficients of lithium cations for all investigated values of x represent a specific feature of the kinetics of intercalation in LixAl2(OH)(2)[Si2O5](2).

引用

页码：109 / 116

页数：8

共 17 条

[1]

[Anonymous], FIZ TEKH POLUPROV

[2]

[Anonymous], 1991, ELECTROCHEMICAL IMPE

[3]

Barsoukov E, 2005, IMPEDANCE SPECTROSCOPY: THEORY, EXPERIMENT, AND APPLICATIONS, 2ND EDITION, pXII

[4]

Baryshnikov K. A., 2012, FIZ TVERD TELA, V54, P442

[5]

ERMOLOVICH IB, 1997, FIZ TEKH POLUPROV, V31, P503

[6]

Korovin N. V., 1998, ELEKTROKHIMIYA, V34, P748

[7]

Korovin NV, 1999, ELEKTROKHIMIYA, V35, P738

[8]

McKinnon W. R., 1983, Modern aspects of electrochemistry. No.15, P235

[9] ALKALI-METAL-INTERCALATED TRANSITION-METAL DISULFIDES - A THERMODYNAMIC MODEL [J].

NAGELBERG, AS ;

WORRELL, WL .

JOURNAL OF SOLID STATE CHEMISTRY, 1981, 38 (03) :321-334

[10]

Onishchenko D. V., 2007, ELEKT NAUCH ZH ISSLE, P232

← 1 2 →