Reactivity of a Ru(III)-hydroxo complex in substrate oxidation in water

被引：20
作者：
Ohzu, Shingo [1 ]
Ishizuka, Tomoya [1 ]
Kotani, Hiroaki [1 ]
Kojima, Takahiko [1 ]
机构：
[1] Univ Tsukuba, Fac Pure & Appl Sci, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 95期
关键词：
HYDROGEN-ATOM ABSTRACTION; COUPLED ELECTRON-TRANSFER; HYDROXIDE COMPLEX; LIPOXYGENASE; MECHANISM; ACID; SULFOXIDATION; CHEMISTRY; PHENOLS; ION;
D O I：
10.1039/c4cc07488b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mononuclear Ru-III-OH complex oxidizes substrates such as hydroquinones in water through a pre-equilibrium process based on adduct formation by hydrogen bonding between the Ru-III-OH complex and the substrates. The reaction mechanism switches from hydrogen atom transfer to electron transfer depending on the oxidation potential of substrates.
引用
收藏
页码：15018 / 15021
页数：4
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