TEM analysis of Gd5(SixGe1-x)4, where x=1/2

被引:9
作者
Meyers, JS
Chumbley, S [1 ]
Laabs, F
Pecharsky, AO
机构
[1] Iowa State Univ, Ames Lab, Ames, IA 50011 USA
[2] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA
关键词
transmission electron microscopy; rare earth; phase transition; ferroelastic; Gd5Si2Ge2;
D O I
10.1016/S1359-6454(02)00227-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The material Gd-5(SixGe1-x)(4), with x=1/2 was investigated using transmission electron microscopy. The material possesses a complex crystallographic structure and undergoes a unique, reversible, transformation at low temperatures and an irreversible high temperature transformation. The high, room and low temperature microstructures of arc-melted and heat treated samples are reported. Direct observation of the transformation with a discussion on the mechanism of the reversible, low temperature, phase transformation is detailed. (C) 2002 Acta Materialia Inc. Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:61 / 70
页数:10
相关论文
共 50 条
  • [41] Sites and Mobility of Lithium along the Li1+x Ti2-x In x (PO4)3 (0 ≤ x ≤ 2) Series Deduced by XRD, NMR, and Impedance Spectroscopy
    Kahlaoui, Radhouene
    Arbi, Kamel
    Sobrados, Isabel
    Jimenez, Ricardo
    Ternane, Riadh
    Sanz, Jesus
    INORGANIC CHEMISTRY, 2024, 63 (17) : 7806 - 7819
  • [42] Synthesis and Structural Transformations of (Gd1-xCex)2Zr2O7+x: An Analogue for Pu Immobilization
    Zhao Pei-Zhu
    Li Lin-Yan
    Xu Sheng-Ming
    Zhang Qin
    ACTA PHYSICO-CHIMICA SINICA, 2013, 29 (06) : 1168 - 1172
  • [43] PHASE-TRANSITIONS IN MIXED-CRYSTAL SYSTEM (NH4)2(BEF4)1-X(SO4)X
    ONO, Y
    HIKITA, T
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1992, 61 (06) : 2141 - 2146
  • [44] High-pressure structural studies of Li x La1/3NbO3 (x=1/6, 1/3, 1/2, 2/3)
    Noked, O.
    Melchior, A.
    Shuker, R.
    Chizawa, S.
    Liermann, H. P.
    Kennedy, B. J.
    Nakayama, M.
    Sterer, E.
    PHYSICS AND CHEMISTRY OF MINERALS, 2014, 41 (05) : 333 - 340
  • [45] Raman phonon anomalies in Sr(Fe1-x Co x )2As2
    Yang, Yanxing
    Zhang, Hewei
    Zhuang, Haizheng
    CHINESE PHYSICS B, 2022, 31 (02)
  • [46] (Naxk1-x)2Ta4O11 (x ≈ 0.93) piezoelectric phase from the transformation of Ta2O5 thin films of monoclinic structure
    Le Gallic, M.
    Roussel, H.
    JOURNAL OF SOLID STATE CHEMISTRY, 2013, 200 : 143 - 149
  • [47] Effect of deuteration on the barocaloric properties of complex vanadates (NH4)3VOxF6−x (x: 1, 2)
    Bogdanov E.V.
    Gorev M.V.
    Flerov I.N.
    Solid State Sciences, 2022, 133
  • [48] Bond-length fluctuation in the orthorhombic 3 x 3 x 1 superstructure of LiMn2O4 spinel
    Ishizawa, Nobuo
    Tateishi, Kenji
    Oishi, Shuji
    Kishimoto, Shunji
    AMERICAN MINERALOGIST, 2014, 99 (8-9) : 1528 - 1536
  • [49] Atomistic Simulation and Characterization of Spinel Li1+xMn2O4 (0 ≤ x ≤ 1) Nanoparticles
    Ledwaba, Raesibe S.
    Sayle, Dean C.
    Ngoepe, Phuti E.
    ACS APPLIED ENERGY MATERIALS, 2020, 3 (02) : 1429 - 1438
  • [50] X-ray diffraction study of (TlInSe2)1-x (TlGaTe2) x crystal system
    Sheleg, A. U.
    Zub, E. M.
    Yachkovskii, A. Ya.
    Mustafaeva, S. N.
    Kerimova, E. M.
    CRYSTALLOGRAPHY REPORTS, 2012, 57 (02) : 283 - 285